bis(η6-hexadeuterated benzene)chromium

Base Information

• Chemical Name: bis(η6-hexadeuterated benzene)chromium
• CAS No.: 11077-44-4
• Molecular Formula: C₁₂H₁₂Cr
• Molecular Weight: 220.128
• Mol file: 11077-44-4.mol

Synonyms:

Chemical Property of bis(η6-hexadeuterated benzene)chromium

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of bis(η6-hexadeuterated benzene)chromium

There total 1 articles about bis(η6-hexadeuterated benzene)chromium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

chromium (7440-47-3) → chromium + chromium dimer (12184-82-6) + bis(η6-hexadeuterated benzene)chromium (11077-44-4) + Cr3*2C6D6=Cr3(C6D6)2

Guidance literature:

With benzene-d6; In solid matrix; Irradiation (UV/VIS); depositing Cr vapor in neat C6D6 or C6D6/Ar (12 K), irradiation (395 nm, 1 kW Xe lamp); detected by UV and Raman spectroscopy;

DOI:10.1007/BF01427004

Reference yield:

bis(η6-hexadeuterated benzene)chromium (11077-44-4) + benzaldehyde-d6 (17901-93-8) → Bis{D10}(benzoyl-η6-benzene)chromium (89252-48-2)

Guidance literature:

With n-butyllithium; air; water; deuterated bis-(η6-benzene)chromium was metalated under N2 with n-butylLi in the presence of TMEDA; addn. of (D6)benzaldehyde with stirring at room temp.; after 12 h stirring, hydrolysis with water, addn. of H2O/CH3OH; washed, extn. with toluene;

Reference yield:

bis(η6-hexadeuterated benzene)chromium (11077-44-4) + benzaldehyde-d6 (17901-93-8) → (η6-{D6}benzene)({D5}benzoyl-η6-{D5}benzene)chromium (89252-47-1)

Guidance literature:

With n-butyllithium; air; water; deuterated bis(η-6-benzene)chromium was metalated under N2 with n-butylLi in presence of TMEDA and (D6)benzaldehyde was added; after 12 h stirring at room temp. hydrolysis with water (2 h );; extn. with toluene, extract washed with water, dried; sepn. by chromy.;;

upstream raw materials:

chromium

Downstream raw materials:

Bis{D10}(benzoyl-η6-benzene)chromium

(η6-{D6}benzene)({D5}benzoyl-η6-{D5}benzene)chromium