[Ru(BH(3,5-dimethyl-4-bromo-pyrazol-1-yl)3)(3,5-dimethyl-4-bromo-pyrazole-1-yl)(3,5-dimethyl4-bromo-pyrazol-1-ylH)2]

Base Information

• Chemical Name: [Ru(BH(3,5-dimethyl-4-bromo-pyrazol-1-yl)3)(3,5-dimethyl-4-bromo-pyrazole-1-yl)(3,5-dimethyl4-bromo-pyrazol-1-ylH)2]
• CAS No.: 878496-20-9
• Molecular Formula: C₃₀H₃₉BBr₆N₁₂Ru
• Molecular Weight: 1159.03
• Mol file: 878496-20-9.mol

Synonyms:

Chemical Property of [Ru(BH(3,5-dimethyl-4-bromo-pyrazol-1-yl)3)(3,5-dimethyl-4-bromo-pyrazole-1-yl)(3,5-dimethyl4-bromo-pyrazol-1-ylH)2]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Ru(BH(3,5-dimethyl-4-bromo-pyrazol-1-yl)3)(3,5-dimethyl-4-bromo-pyrazole-1-yl)(3,5-dimethyl4-bromo-pyrazol-1-ylH)2]

There total 2 articles about [Ru(BH(3,5-dimethyl-4-bromo-pyrazol-1-yl)3)(3,5-dimethyl-4-bromo-pyrazole-1-yl)(3,5-dimethyl4-bromo-pyrazol-1-ylH)2] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 24.0%

4-Bromo-3,5-dimethylpyrazole (3398-16-1) + trans-{RuCl2(C6H5CN)4} (21503-87-7,51014-03-0) + potassium hydrotris(4-bromo-3,5-dimethylpyrazol-1-yl)borate → [Ru(BH(3,5-dimethyl-4-bromo-pyrazol-1-yl)3)(3,5-dimethyl-4-bromo-pyrazole-1-yl)(3,5-dimethyl4-bromo-pyrazol-1-ylH)(benzonitrile)] (878496-21-0) + [Ru(BH(3,5-dimethyl-4-bromo-pyrazol-1-yl)3)(3,5-dimethyl-4-bromo-pyrazole-1-yl)(3,5-dimethyl4-bromo-pyrazol-1-ylH)2] (878496-20-9)

Guidance literature:

In benzene; under N2; Ru-contg. compd. (0.34 mmol) was treated with KB-contg. compd.(0.79 mmol) in benzene; the mixt. was heated with a ligand (1.71 mmol) under reflux overnight; benzene-extd. material was chromd. on a silica-gel column; benzene elution; elem. anal.;

DOI:10.1016/j.ica.2005.08.005

Reference yield: 2.0%

trans-{RuCl2(C6H5CN)4} (21503-87-7,51014-03-0) + potassium hydrotris(4-bromo-3,5-dimethylpyrazol-1-yl)borate → [Ru(BH(3,5-dimethyl-4-bromo-pyrazol-1-yl)3)(3,5-dimethyl-4-bromo-pyrazole-1-yl)(3,5-dimethyl4-bromo-pyrazol-1-ylH)(benzonitrile)] (878496-21-0) + [Ru(BH(3,5-dimethyl-4-bromo-pyrazol-1-yl)3)(3,5-dimethyl-4-bromo-pyrazole-1-yl)(3,5-dimethyl4-bromo-pyrazol-1-ylH)2] (878496-20-9)

Guidance literature:

In benzene; under N2; Ru-contg. compd. was treated with KB-contg. compd. in refluxing benzene; benzene-extd. material was chromd. on a silica-gel column; benzene elution; elem. anal.;

DOI:10.1016/j.ica.2005.08.005

upstream raw materials:

trans-{RuCl₂(C₆H₅CN)4}

4-Bromo-3,5-dimethylpyrazole