fac-tetracarbonyl(triphenyl phosphite)(1,2-bis(diphenylphosphino)ethane)molybdenum

Base Information

Chemical Name:fac-tetracarbonyl(triphenyl phosphite)(1,2-bis(diphenylphosphino)ethane)molybdenum
CAS No.:1032101-59-9
Molecular Formula:C₄₇H₃₉MoO₆P₃
Molecular Weight:888.684
Hs Code.:

Synonyms:

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Chemical Property of fac-tetracarbonyl(triphenyl phosphite)(1,2-bis(diphenylphosphino)ethane)molybdenum

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Technology Process of fac-tetracarbonyl(triphenyl phosphite)(1,2-bis(diphenylphosphino)ethane)molybdenum

There total 2 articles about fac-tetracarbonyl(triphenyl phosphite)(1,2-bis(diphenylphosphino)ethane)molybdenum which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 101-02-0
triphenyl phosphite

: 19349-52-1
fac-((pyridine)-1,2-bis(diphenylphosphino)ethane)Mo(CO)3

: 1032101-59-9,1032342-67-8
fac-tetracarbonyl(triphenyl phosphite)(1,2-bis(diphenylphosphino)ethane)molybdenum

Guidance literature:: In hexane; toluene; Irradiation (UV/VIS); N2-atmosphere, stirring (45°C, 1 h), filtration (hot), addn. of hexane; pptn. on standing (overnight, 4°C), sepn. (suction filtration), washing (hexane), drying (vac.); elem. anal.;

Reference yield:

: 101-02-0
triphenyl phosphite

: tricarbonyltris(DMF)molybdenum

: 1663-45-2
1,2-bis-(diphenylphosphino)ethane

: 1032101-59-9,1032342-67-8
fac-tetracarbonyl(triphenyl phosphite)(1,2-bis(diphenylphosphino)ethane)molybdenum

: 1032342-67-8
mer-tetracarbonyl(triphenyl phosphite)(1,2-bis(diphenylphosphino)ethane)molybdenum

Guidance literature:: In N,N-dimethyl-formamide; toluene; soln. of Mo complex and Ph2PCH2CH2PPh2 in dry toluene-DMF stirred at 20°C for 3 h; P(OEt)3 in toluene added; heated at 90 or 135°Cfor 12 h; cooled to 20°C; filtered through Celite; filtrate concd. under reduced pressure; mixt. of fac and mer isomers (50:50, total yield 77% at 90°C or 10:90, total yield 78% at 135°C) obtained;
DOI:10.1016/j.jorganchem.2008.02.008