1,4-Bis(benzoyloxy)benzene

Base Information

• Chemical Name: 1,4-Bis(benzoyloxy)benzene
• CAS No.: 14210-97-0
• Molecular Formula: C20H14O4
• Molecular Weight: 318.329
• Mol file: 14210-97-0.mol

Synonyms:benzene-1,4-diyl dibenzoate;1,4-bis-benzoyloxy-benzene;1,4-phenylene dibenzoate;hydroquinone dibenzoate;p-phenylene dibenzoate;benzene-1,4-diyl benzoate;1,4-Benzenediol, dibenzoate;

Chemical Property of 1,4-Bis(benzoyloxy)benzene

Chemical Property:

• Melting Point: 204 °C
• Boiling Point: 150 - 250 °C (2 mmHg)
• PSA: 52.60000
• Density: 1.242±0.06 g/cm3(Predicted)
• LogP: 4.12500

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1,4-Bis(benzoyloxy)benzene

There total 20 articles about 1,4-Bis(benzoyloxy)benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

benzoic acid anhydride (93-97-0) + hydroquinone (123-31-9,8027-02-9) → 1,4-dibenzoyloxybenzene (14210-97-0)

Guidance literature:

With bismuth(lll) trifluoromethanesulfonate; In acetonitrile; for 1h; Heating;

DOI:10.1016/S0040-4020(01)00521-X

Reference yield: 93.0%

vinyl benzoate (769-78-8,24991-32-0) + hydroquinone (123-31-9,8027-02-9) → 1,4-dibenzoyloxybenzene (14210-97-0)

Guidance literature:

With 1,4-diaza-bicyclo[2.2.2]octane; In neat (no solvent); at 70 - 140 ℃; for 0.183333h; Microwave irradiation;

DOI:10.1039/c5nj01436k

Reference yield: 88.0%

N-benzyl-N-(tert-butoxycarbonyl)-benzamide (85909-02-0) + hydroquinone (123-31-9,8027-02-9) → 1,4-dibenzoyloxybenzene (14210-97-0)

Guidance literature:

With sodium t-butanolate; In toluene; at 150 ℃; for 36h; Sealed tube;

DOI:10.1007/s11426-020-9883-3

upstream raw materials:

1,3,4,5-tetrahydroxy-cyclohexanecarboxylic acid

benzoyl chloride

hydroquinone

p-benzoquinone

Downstream raw materials:

2,5-dibenzoyl-1,4-dihydroxybenzene

(2-hydroxy-5-benzoyloxyphenyl)(phenyl)methanone

4-hydroxyphenyl benzoate

1,2-ethanediol, dibenzoate