meso-⁽¹³⁾C-(tetraphenylchlorinato)iron(III)ClO₄

Base Information

• Chemical Name: meso-⁽¹³⁾C-(tetraphenylchlorinato)iron(III)ClO₄
• CAS No.: 909913-55-9
• Molecular Formula: C₄₄H₃₀ClFeN₄O₄
• Molecular Weight: 774.003
• Mol file: 909913-55-9.mol

Synonyms:

Chemical Property of meso-⁽¹³⁾C-(tetraphenylchlorinato)iron(III)ClO₄

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of meso-⁽¹³⁾C-(tetraphenylchlorinato)iron(III)ClO₄

There total 1 articles about meso-⁽¹³⁾C-(tetraphenylchlorinato)iron(III)ClO₄ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(7,8-dihydro-5,10,15,20-tetraphenylporphyrin) iron(III) chloride (94483-24-6) + silver perchlorate → meso-(13)C-(tetraphenylchlorinato)iron(III)ClO4 (909913-55-9)

Guidance literature:

In tetrahydrofuran; byproducts: AgCl; THF added to mixt. of AgClO4 and Fe compd.; stirred at room temp. for 20min; solvent evapd.; CH2Cl2 added; filtered; repeated twice; filtrate evapd.;dried in vac. at 25°C for 4 h;

DOI:10.1021/ic060508o

Reference yield:

meso-(13)C-(tetraphenylchlorinato)iron(III)ClO4 (909913-55-9) + tert-butylisonitrile (119072-55-8,7188-38-7) → meso-(13)C-[(tetraphenylchlorinato)iron(III)(t-BuNC)2]ClO4 (910027-17-7)

Guidance literature:

In dichloromethane-d2; in NMR tube; CD2Cl2 added to mixt. of Fe compd. and t-BuNC (3 equiv.); not isolated; detd. by (13)C NMR spectra;

DOI:10.1021/ic060508o

Reference yield:

pyridine-4-carbonitrile (100-48-1) + meso-(13)C-(tetraphenylchlorinato)iron(III)ClO4 (909913-55-9) → meso-(13)C-[(tetraphenylchlorinato)iron(III)(4-CNPy)2]ClO4

Guidance literature:

In dichloromethane-d2; in NMR tube; CD2Cl2 added to mixt. of Fe compd. and NC5H4-4-CN (10 equiv.); not isolated; detd. by (13)C NMR spectra;

DOI:10.1021/ic060508o

upstream raw materials:

(7,8-dihydro-5,10,15,20-tetraphenylporphyrin) iron(III) chloride

Downstream raw materials:

meso-⁽¹³⁾C-[(tetraphenylchlorinato)iron(III)(t-BuNC)2]ClO₄