cyclohexyl 4-methylbenzenesulfinate

Base Information

• Chemical Name: cyclohexyl 4-methylbenzenesulfinate
• CAS No.: 23730-24-7
• Molecular Formula: C13H18 O2 S
• Molecular Weight: 238.351
• Mol file: 23730-24-7.mol

Synonyms:p-Toluenesulfinicacid, cyclohexyl ester (8CI); Cyclohexyl p-toluenesulfinate; NSC 150800

Chemical Property of cyclohexyl 4-methylbenzenesulfinate

Chemical Property:

• Vapor Pressure: 2.99E-05mmHg at 25°C
• Boiling Point: 366.9°C at 760 mmHg
• Flash Point: 175.7°C
• Density: 1.17g/cm³

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of cyclohexyl 4-methylbenzenesulfinate

There total 10 articles about cyclohexyl 4-methylbenzenesulfinate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

p-toluene sulfinic acid (536-57-2) + cyclohexanol (108-93-0) → cyclohexyl 4-methylbenzenesulfinate (23730-24-7)

Guidance literature:

With pyridine; chlorophosphoric acid diphenyl ester; In dichloromethane; for 15h; Product distribution; Ambient temperature; variation of reagents, temperature and reaction time;

DOI:10.1248/cpb.30.1646

Reference yield: 91.0%

para-thiocresol (106-45-6) + cyclohexanol (108-93-0) → cyclohexyl 4-methylbenzenesulfinate (23730-24-7)

Guidance literature:

With tetrabutylammonium tetrafluoroborate; In acetonitrile; at 20 ℃; for 4h; Electrochemical reaction;

DOI:10.1002/jccs.201900246

Reference yield: 86.0%

[(p-methylphenyl)sulfonylmethyl]isonitrile (38622-91-2,36635-61-7) + cyclohexanol (108-93-0) → cyclohexyl 4-methylbenzenesulfinate (23730-24-7)

Guidance literature:

With di-isopropyl azodicarboxylate; triphenylphosphine; In tetrahydrofuran; at 0 - 20 ℃;

DOI:10.1002/adsc.201600997

upstream raw materials:

<2-(p-tolylsulfonyl)hydrazino>cyclohexane

p-toluenesulfonyl chloride

cyclohexanol

p-toluene sulfinic acid

Downstream raw materials:

1-bromocyclohexane

1,2-dibromocyclohexane

toluene-p-sulfonyl bromide