[(C₅H₅)2MoCH₃CHCHCH₂]⁽¹⁺⁾*CH₃C₆H₄SO₃^(1-)=[(C₅H₅)2MoCH₃CHCHCH₂](CH₃C₆H₄SO₃)

Base Information

• Chemical Name: [(C₅H₅)2MoCH₃CHCHCH₂]⁽¹⁺⁾*CH₃C₆H₄SO₃^(1-)=[(C₅H₅)2MoCH₃CHCHCH₂](CH₃C₆H₄SO₃)
• CAS No.: 688772-10-3
• Molecular Formula: C₇H₇O₃S*C₁₄H₁₇Mo
• Molecular Weight: 452.426
• Mol file: 688772-10-3.mol

Synonyms:

Chemical Property of [(C₅H₅)2MoCH₃CHCHCH₂]⁽¹⁺⁾*CH₃C₆H₄SO₃^(1-)=[(C₅H₅)2MoCH₃CHCHCH₂](CH₃C₆H₄SO₃)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [(C₅H₅)2MoCH₃CHCHCH₂]⁽¹⁺⁾*CH₃C₆H₄SO₃^(1-)=[(C₅H₅)2MoCH₃CHCHCH₂](CH₃C₆H₄SO₃)

There total 2 articles about [(C₅H₅)2MoCH₃CHCHCH₂]⁽¹⁺⁾*CH₃C₆H₄SO₃^(1-)=[(C₅H₅)2MoCH₃CHCHCH₂](CH₃C₆H₄SO₃) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 30.0%

homoalylic alcohol (627-27-0) + bis(η5-cyclopentadinyl)dihydridomolybdenum + toluene-4-sulfonic acid (104-15-4) → [(C5H5)2MoCH3CHCHCH2](1+)*CH3C6H4SO3(1-)=[(C5H5)2MoCH3CHCHCH2](CH3C6H4SO3) (688772-10-3)

Guidance literature:

In methanol; under Ar or N2; Mo-contg. compd. (0.815 mmol) and TsOH (0.807 mmol) wereloaded in a Schlenk tube; an excess of homoallyl alc. was vac.-transfer red into the tube; the mixt. was cooled to -78°C and degassed; stirring at 50°C for 6 h; the volatiles were removed under vac.; extn. with MeOH; the ext. was filtered, concd. in vac., dissolved in acetone and cooled; recrystn. from THF/Et2O afforded cyclic compd.; the residue was washed with EtOH and hexane, dried under vac.; (1)H NMR data;

DOI:10.1016/j.jorganchem.2003.12.037

Reference yield:

homoalylic alcohol (627-27-0) + bis(η5-cyclopentadienyl)(3-hydroxy-2-methylpropyl-C,O)molybdenum(IV) p-toluenesulfonate + toluene-4-sulfonic acid (104-15-4) → [(C5H5)2MoCH3CHCHCH2](1+)*CH3C6H4SO3(1-)=[(C5H5)2MoCH3CHCHCH2](CH3C6H4SO3) (688772-10-3)

Guidance literature:

In methanol; under Ar or N2; at room temp. in MeOH soln. within 10 h; monitoring by (1)H NMR spectra;

DOI:10.1016/j.jorganchem.2003.12.037

upstream raw materials:

homoalylic alcohol

toluene-4-sulfonic acid