chloro(triphenylarsine)dinitrosyldicarbonyltungsten(II) chloride

Base Information

• Chemical Name: chloro(triphenylarsine)dinitrosyldicarbonyltungsten(II) chloride
• CAS No.: 82179-81-5
• Molecular Formula: C₂₀H₁₅AsClN₂O₄W*Cl
• Molecular Weight: 677.028
• Mol file: 82179-81-5.mol

Synonyms:

Chemical Property of chloro(triphenylarsine)dinitrosyldicarbonyltungsten(II) chloride

Chemical Property:

Purity/Quality:

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Technology Process of chloro(triphenylarsine)dinitrosyldicarbonyltungsten(II) chloride

There total 2 articles about chloro(triphenylarsine)dinitrosyldicarbonyltungsten(II) chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 38.2%

o-phenanthroline(triphenylarsine)tricarbonyltungsten(0) + nitrosylchloride (2696-92-6) → dichloro(o-phenanthroline)dinitrosyltungsten(II) (81818-06-6,146387-27-1) + chloro(triphenylarsine)dinitrosyldicarbonyltungsten(II) chloride (82179-81-5)

Guidance literature:

In benzene; dil. benzene soln. of NOCl was added to solid complex, under N2, stirred at room temp., after appearance pf ppt. stirred for 1 h, yields of dichloro isomers are 27.0-34.3 %; liq. phase was decanted, the solid was washed with benzene, dried in vac., elem. anal., to supernatant was added hexane, the ppt. was washed several times with hexane, dried in vac., elem. anal.;

Reference yield:

2,2'bipyridyl(triphenylarsine)tricarbonyltungsten(0) + nitrosylchloride (2696-92-6) → dichloro(2,2'-bipyridyl)dinitrosyltungsten(II) (82179-82-6) + chloro(triphenylarsine)dinitrosyldicarbonyltungsten(II) chloride (82179-81-5)

Guidance literature:

In benzene; dil. benzene soln. of NOCl was added to solid complex, under N2, stirred at room temp., after appearance pf ppt. stirred for 1 h, yields of dichloro isomers are 30.4-36.0 %; liq. phase was decanted, the solid was washed with benzene, dried in vac., elem. anal., to supernatant was added hexane, the ppt. was washed several times with hexane, dried in vac., elem. anal.;

upstream raw materials:

nitrosylchloride