2696-92-6Relevant articles and documents
Coates,Finney
, p. 2444 - 2444 (1914)
New systems for classical nitrosohalogenation of alkenes 2. Generation of nitrosyl chloride in AgNO2-SOCl2 and AgNO 3-SOCl2 systems
Bondarenko,Gavrilova,Tikhanushkina,Zyk
, p. 2145 - 2149 (2005)
Study of the reactions of compounds of the norbornene series demonstrated that the AgNO2-SOCl2 and AgNO3-SOCl2 systems serve as nitrosochlorinating agents under the conditions of electrophilic addition. X-ray di
Bent, H. A.,Crawford, B.
, p. 1793 - 1797 (1957)
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Steacie, E. W. R.,Smith, W. McF.
, p. 145 - 149 (1938)
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Gintz, F. P.,Goddard, D. R.,Collis, M. J.
, (1958)
Atmospheric chemistry of C2F5CHO: reaction with Cl atoms and OH radicals, IR spectrum of C2F5C(O)O2NO2
Andersen, M. P. Sulbaek,Hurley, M. D.,Wallington, T. J.,Ball, J. C.,Martin, J. W.,Ellis, D. A.,Mabury, S. A.,Nielsen, O. J.
, p. 28 - 36 (2003)
Smog chamber/FTIR techniques were used to measure k(Cl + C2F5CHO) = (1.96+/-0.28) x 10-12 and k(OH + C2F5CHO) = (5.26+/-0.80) x 10-13 cm3 molecule-1 s-1 in 700 Torr of N2 or air at 296+/-2 K. The Cl i
Burns, W. G.,Dainton, F. S.
, p. 21 - 24 (1952)
Kinetic study of an autocatalytic reaction: Nitrosation of formamidine disulfide
Francisco, Vitor,Garcia-Rio, Luis,Antonio Moreira, Jose,Stedman, Geoffrey
, p. 2292 - 2298 (2008)
The reaction kinetics for the acid nitrosation of formamidine disulfide (FDS) show an autocatalytic behavior that arises from the fact that the thiocyanate ion formed as a product acts as a powerful catalyst for the nitrosation reaction. In the presence of added nucleophiles the suppression of the autocatalytic route results from competition for the nitrous acid between the added halides and the thiocyanate anion, which is formed as a reaction product. Analysis of the kinetic data enabled extraction of the bimolecular rate constants, kNO+ = (3.2 ± 1.8) × 1010 M -1 s-1; kNOSCN = (2.1 ± 0.2) × 105 M-1 s-1; kNOBr = (9.4 ± 0.2) × 106 M-1 s1 and kNOCl = (4.0 ± 0.2) × 107 M-1 s-1, for the pathways catalyzed by SCN-, Br- and Cl-, respectively. Kinetic results are consistent with the attack on the nitrosating agent as the rate limiting step, i.e., the nitrosation of FDS behaves in a similar manner to the nitrosation of an amine. Rather different behavior is found for other substrates with an imino moiety adjacent to an amino nitrogen, such as the guanidines, which react by a mechanism in which the rate limiting step is the reorganization of the nitrosated substrate. The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2008.
Welinsky, J.,Taylor, H. A.
, p. 466 - 472 (1938)
New details concerning the reactions of nitric oxide with vanadium tetrachloride
Hayton, Trevor W.,Patrick, Brian O.,Legzdins, Peter
, p. 7227 - 7233 (2004)
The slow addition of NO to a CCl4 solution of VCl4 reproducibly forms the known polymer [V(NO)3Cl2 ]n as a dark brown powder. Treatment of a CH2Cl 2 suspension of [V(NO)3Cl2]n with excess THF generates mer-(THF)3V(NO)Cl2 (1) which can be isolated as an orange crystalline material in 55% yield. The reaction of 1 with excess MeCN or 1 equiv of trimpsi (trimpsi = tBuSi(CH 2PMe2)3) provides yellow-orange (MeCN) 3V(NO)Cl2·MeCN (2·MeCN) and yellow (trimpsi)V(NO)Cl2 (3), respectively. A black, crystalline complex formulated as [NO][VCl5] (4) is formed by the slow addition of NO to neat VCl4 or by the reaction of excess CINO with neat VCl 4. Complex 4 is extremely air- and moisture-sensitive, and IR spectroscopy suggests that in solutions and in the gas phase it dissociates back into VCl4 and CINO. Reaction of 4 with excess [NEt 3(CH2Ph)]CI generates [NEt3(CH 2Ph)]2[VCl6]·2CH2Cl 2 (5·2CH2Cl2), which can be isolated as deep-red crystals in 51% yield. All new complexes have been characterized by conventional spectroscopic methods, and the solid-state molecular structures of 1, 2·MeCN, and 5·2CH2Cl2 have been established by single-crystal X-ray diffraction analyses.
Temperature Dependence of the OH + ClNO Reaction: Evidence for two Competing Reaction Channels
Finlayson-Pitts, B. J.,Ezell, M. J.,Grant, C. E.
, p. 17 - 19 (1986)
The temperature dependence of the reaction of OH with nitrosyl chloride, ClNO, has been studied from 263 to 373 K in a fast-flow discharge system.The decay of OH in the presence of excess ClNO was followed by resonance fluorescence at 309.5 nm.The total pressure was 1.05+/-0.05 torr in He as the carrier gas.The rate constant increases both above and below room temperature suggesting the existence of two competing reaction paths, a direct abstraction reaction, HO + ClNO -> HOCl + NO (1a) and one involving formation of an intermediate complex, HO + ClNO * -> HONO + Cl (1b).This supports the interpretation of the room temperature product data of Poulet and co-workers.
Markowitz, M. M.,Ricci, J. E.,Goldman, R. J.,Winternitz, P. E.
, p. 159 - 161 (1960)
Resonance Raman spectroscopy in the dissociative A band of nitrosyl chloride
Mackey,Johnson,Kittrell,Le,Kinsey
, p. 6631 - 6640 (2001)
Resonance Raman spectra were obtained for CINO at three wavelengths in the ultraviolet A band. Twelve previously unobserved vibrational levels in the ground state were observed. These new levels, together with previously known vibrational levels, allowed the construction of a large amplitude vibrational model valid in and beyond the Franck-Condon region. The ground state surface showed a large degree of separability in Jacobi coordinates even in the triatomic molecular region.
Anhydrous Dinitrogen Trioxide Solutions for Br?nsted Acid Free Nitrous Acid Chemistry
Rosadiuk, Kristopher A.,Bohle, D. Scott
, p. 5461 - 5465 (2017/12/26)
Dinitrogen trioxide, N2O3, is readily prepared and stabilized in high concentrations in dry organic solvents at normal working temperatures. These conditions allow for facile acid and water free nitrosation and nitration reactions fo
Reaction of trans-[RuNO(NH3)4(OH)]Cl2 with nitric acid and synthesis of ammine(nitrato)nitrosoruthenium complexes
Kabin,Emel'yanov,Vorob'yev,Alferova,Tkachev,Baidina
, p. 1146 - 1153 (2012/10/08)
The reaction of trans-[RuNO(NH3)4(OH)]Cl2 with nitric acid has been studied. Reaction prod- ucts have been identified by IR spectroscopy, NMR, mass spectrometry, powder and single-crystal X-ray dif- fraction, and chemical
