[PtCl(κ2-(2-methylselenoethyl)diphenylphosphine)((2-phenylthioethyl)diphenylphosphine)]Cl

Base Information

• Chemical Name: [PtCl(κ2-(2-methylselenoethyl)diphenylphosphine)((2-phenylthioethyl)diphenylphosphine)]Cl
• CAS No.: 1209497-15-3
• Molecular Formula: C₃₅H₃₆ClP₂PtSSe*Cl
• Molecular Weight: 895.63
• Mol file: 1209497-15-3.mol

Synonyms:

Chemical Property of [PtCl(κ2-(2-methylselenoethyl)diphenylphosphine)((2-phenylthioethyl)diphenylphosphine)]Cl

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [PtCl(κ2-(2-methylselenoethyl)diphenylphosphine)((2-phenylthioethyl)diphenylphosphine)]Cl

There total 2 articles about [PtCl(κ2-(2-methylselenoethyl)diphenylphosphine)((2-phenylthioethyl)diphenylphosphine)]Cl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

[Pt(κ2-(2-methylselenoethyl)diphenylphosphine)(κ2-(2-phenylthioethyl)diphenylphosphine)](BF4)2 + tetramethlyammonium chloride (75-57-0) → [PtCl(κ2-(2-methylselenoethyl)diphenylphosphine)((2-phenylthioethyl)diphenylphosphine)]Cl (1209497-15-3)

Guidance literature:

In methanol; dichloromethane; soln. of Me4NCl in MeOH added to soln. of Pt complex in CH2Cl2; 20 min; monitored by (31)P NMR spectra;

DOI:10.1021/ic901991w

Reference yield:

dichloro( 1,5-cyclooctadiene)platinum(ll) (12080-32-9) + [2-(methylseleno)ethyl](diphenyl)phophine (1209497-10-8) + (2-(phenylthio)ethyl)diphenylphosphine (19297-97-3) → [PtCl(κ2-(2-methylselenoethyl)diphenylphosphine)((2-phenylthioethyl)diphenylphosphine)]Cl (1209497-15-3)

Guidance literature:

In 1,2-dichloro-ethane; soln. of Ph2PCH2CH2SeMe in 1,2-dichloroethane added dropwise to soln. ofPt complex in 1,2-dichloroethane at room temp.; stirred for 5 min; Ph2P CH2CH2SPh in 1,2-dichloroethane added dropwise; 20 min; solvent reduced in vac.; Et2O added; filtered; solid washed with ether; elem. anal.;

DOI:10.1021/ic901991w

Reference yield:

sodium tetrafluoroborate (13755-29-8) + [PtCl(κ2-(2-methylselenoethyl)diphenylphosphine)((2-phenylthioethyl)diphenylphosphine)]Cl (1209497-15-3) → [Pt(κ2-(2-methylselenoethyl)diphenylphosphine)(κ2-(2-phenylthioethyl)diphenylphosphine)](BF4)2

Guidance literature:

In 1,2-dichloro-ethane; NaBF4 added to soln. of Pt complex in 1,2-dichloroethane; stirred for 24h; passed through Celite; vol. reduced in vac.; Et2O added; filtered; ppt. washed with ether; elem. anal.;

DOI:10.1021/ic901991w

upstream raw materials:

tetramethlyammonium chloride

dichloro( 1,5-cyclooctadiene)platinum(ll)

[2-(methylseleno)ethyl](diphenyl)phophine

(2-(phenylthio)ethyl)diphenylphosphine