trans-[Ru(N⁽⁴⁾-meta-tolyl-2-acetylpyridine thiosemicarbazone)(PPh₃)2Cl]Cl

Base Information

• Chemical Name: trans-[Ru(N⁽⁴⁾-meta-tolyl-2-acetylpyridine thiosemicarbazone)(PPh₃)2Cl]Cl
• CAS No.: 1020544-91-5
• Molecular Formula: C₅₁H₄₆ClN₄P₂RuS*Cl
• Molecular Weight: 980.943
• Mol file: 1020544-91-5.mol

Synonyms:

Chemical Property of trans-[Ru(N⁽⁴⁾-meta-tolyl-2-acetylpyridine thiosemicarbazone)(PPh₃)2Cl]Cl

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of trans-[Ru(N⁽⁴⁾-meta-tolyl-2-acetylpyridine thiosemicarbazone)(PPh₃)2Cl]Cl

There total 2 articles about trans-[Ru(N⁽⁴⁾-meta-tolyl-2-acetylpyridine thiosemicarbazone)(PPh₃)2Cl]Cl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

cis-[Ru(N(4)-meta-tolyl-2-acetylpyridine thiosemicarbazone)(PPh3)2Cl]Cl → trans-[Ru(N(4)-meta-tolyl-2-acetylpyridine thiosemicarbazone)(PPh3)2Cl]Cl (1020263-30-2,1020544-91-5)

Guidance literature:

In dichloromethane-d2; soln. of Ru complex (mixt. of cis and trans isomers 33:67) in CD2Cl2 stored for 24 h; not isolated; monitored by (31)P NMR spectra; mixt. of cis and trans isomers (25:75) obtained;

DOI:10.1016/j.molstruc.2007.04.032

Reference yield:

tris(triphenylphosphine)ruthenium(II) chloride (15529-49-4,41756-81-4) + N(4)-meta-tolyl-2-acetylpyridine thiosemicarbazone (70618-22-3) → trans-[Ru(N(4)-meta-tolyl-2-acetylpyridine thiosemicarbazone)(PPh3)2Cl]Cl (1020263-30-2,1020544-91-5) + cis-[Ru(N(4)-meta-tolyl-2-acetylpyridine thiosemicarbazone)(PPh3)2Cl]Cl

Guidance literature:

In dichloromethane; under Ar; thiosemicarbazone dissolved in CH2Cl2 with gentle heating; cooled to room temp.; Ru complex added; pptd. by addition of Et2O; filtered; ppt. washed with MeOH and Et2O; dried in vac.; elem. anal.; mixt. of cis and trans isomers obtained, total yield 75.5%;

DOI:10.1016/j.molstruc.2007.04.032

upstream raw materials:

tris(triphenylphosphine)ruthenium(II) chloride

N⁽⁴⁾-meta-tolyl-2-acetylpyridine thiosemicarbazone