zinc tetraphenylporphyrin-(OH)3-(OGa(8-hydroxyquinaldinate)2)

Base Information

• Chemical Name: zinc tetraphenylporphyrin-(OH)3-(OGa(8-hydroxyquinaldinate)2)
• CAS No.: 791619-72-2
• Molecular Formula: C₆₄H₄₃GaN₆O₆Zn
• Molecular Weight: 1127.2
• Mol file: 791619-72-2.mol

Synonyms:

Chemical Property of zinc tetraphenylporphyrin-(OH)3-(OGa(8-hydroxyquinaldinate)2)

Chemical Property:

Purity/Quality:

Safty Information:

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Useful:

Technology Process of zinc tetraphenylporphyrin-(OH)3-(OGa(8-hydroxyquinaldinate)2)

There total 1 articles about zinc tetraphenylporphyrin-(OH)3-(OGa(8-hydroxyquinaldinate)2) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 1.0%

2-methyl-8-quinolinol (826-81-3) + gallium(III) nitrate hydrate + 5,10,15,20-tetra(4-p-hydroxyphenyl)-21H,23H-zinc porphyrin (88359-12-0) → zinc tetraphenylporphyrin-(OH)2-(OGa(8-hydroxyquinaldinate)2)2 + zinc tetraphenylporphyrin-(OH)3-(OGa(8-hydroxyquinaldinate)2) (791619-72-2) + zinc tetraphenylporphyrin-(OH)-(OGa(8-hydroxyquinaldinate)2)3 (791619-71-1) + zinc 5,10,15,20-tetrakis(4-(OGa(8-hydroxyquinaldinate)2)phenyl)-porphyrin

Guidance literature:

With sodium hydroxide; In ethanol; water; the gallium salt dissolved in the minimum amount of water and added to an ethanolic soln. of the Zn-complex containing four equivalents of NaOH;8-hydroxyquinaldine in ethanol added and the mixture heated under reflu x overnight (molar ratio: 4.5:1:8); dark blue solid residue recovered after solvent distillation and repeated washing with water, ethanol and chloroform; product contains trace amounts of side products; elem. anal.;

DOI:10.1016/j.inoche.2004.09.025

upstream raw materials:

2-methyl-8-quinolinol

5,10,15,20-tetra(4-p-hydroxyphenyl)-21H,23H-zinc porphyrin