p-anisyldimethylbismuthane

Base Information

Chemical Name:p-anisyldimethylbismuthane
CAS No.:104202-62-2
Molecular Formula:C₉H₁₃BiO
Molecular Weight:346.182
Hs Code.:

Synonyms:

Suppliers and Price of p-anisyldimethylbismuthane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of p-anisyldimethylbismuthane

Chemical Property:

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Technology Process of p-anisyldimethylbismuthane

There total 2 articles about p-anisyldimethylbismuthane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 40.0%

: 104-92-7
1-bromo-4-methoxy-benzene

: 7529-35-3
dimethylbismuthanyl bromide

: 7439-93-2
lithium

: 104202-62-2
p-anisyldimethylbismuthane

Guidance literature:: In tetrahydrofuran; byproducts: Me3Bi, Me4Bi2; (Ar); Li was addded to a soln. of p-Br-anisole mixed at -78°C, vigorous stirred (1.5 h), p-Br-anisole (20 % excess) added, stirred (-78°C, 20 min); filtered, solvent removed (-30--10°C), extracted (cold pentane); solvent was removed, recondensed (0.01 mbar); elem. anal.;

Reference yield:

: 104-92-7
1-bromo-4-methoxy-benzene

: sodium dimethylbismuthide

: 104202-62-2
p-anisyldimethylbismuthane

: 82783-70-8
tetramethyldibismuthane

Guidance literature:: In ammonia; byproducts: NaBr, NaNH2, anisole;

Reference yield:

: 104202-62-2
p-anisyldimethylbismuthane

: 104202-65-5
di(p-anisyl)methylbismuthane

Guidance literature:: byproducts: Me3Bi; treated with a slow N2 stream after 3 weeks at room temp., warmed at approx. 90°C; lower yields of reaction at room temperature after 1 d, under exclusion of light after 5-6 d; cooled; elem. anal.;

upstream raw materials:

1-bromo-4-methoxy-benzene

dimethylbismuthanyl bromide

lithium