cis-[PtCl₂(C₅₉H₈₀N₄P₂O)](5,11,17,23-tetrakis(sulfonato)-25,26,27,28-tetrakis(2-ethoxyethoxy)calix[4]arene)

Base Information

• Chemical Name: cis-[PtCl₂(C₅₉H₈₀N₄P₂O)](5,11,17,23-tetrakis(sulfonato)-25,26,27,28-tetrakis(2-ethoxyethoxy)calix[4]arene)
• CAS No.: 1350660-48-8
• Molecular Formula: C₄₄H₅₂O₂₀S₄*C₅₉H₈₀Cl₂N₄OP₂Pt
• Molecular Weight: 2218.39
• Mol file: 1350660-48-8.mol

Synonyms:

Chemical Property of cis-[PtCl₂(C₅₉H₈₀N₄P₂O)](5,11,17,23-tetrakis(sulfonato)-25,26,27,28-tetrakis(2-ethoxyethoxy)calix[4]arene)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of cis-[PtCl₂(C₅₉H₈₀N₄P₂O)](5,11,17,23-tetrakis(sulfonato)-25,26,27,28-tetrakis(2-ethoxyethoxy)calix[4]arene)

There total 2 articles about cis-[PtCl₂(C₅₉H₈₀N₄P₂O)](5,11,17,23-tetrakis(sulfonato)-25,26,27,28-tetrakis(2-ethoxyethoxy)calix[4]arene) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

cis-[platinum(II)dichloride((C6H4CH2N(H)(C2H5)2)2PC6H3C(CH3)2OC6H3P(C6H4CH2N(H)(C2H5)2)2)](tosylate)4 + 5,11,17,23-tetrasulfonato-25,26,27,28-tetrakis(2-ethoxyethoxy)calix<4>arene, tetrasodium salt → cis-[PtCl2(C59H80N4P2O)](5,11,17,23-tetrakis(sulfonato)-25,26,27,28-tetrakis(2-ethoxyethoxy)calix[4]arene) (1350660-48-8)

Guidance literature:

In d⁽⁴⁾-methanol; byproducts: NaOTf; react. of Pt complex and (NaSO3C6H2(CH2)(OC2H4OC2H5))4 (1 equiv.);

DOI:10.1002/ejic.201100809

Reference yield:

diacetonitriledichloridopalladium(II) (21264-32-4,13869-38-0,13869-42-6) + C(CH3)2O(C6H3P(C6H4CH2NHEt2)2)2(5,11,17,23-tetrakis(sulfonato)-25,26,27,28-tetrakis(2-etoxyethoxy)calix[4]arene) → cis-[PtCl2(C59H80N4P2O)](5,11,17,23-tetrakis(sulfonato)-25,26,27,28-tetrakis(2-ethoxyethoxy)calix[4]arene) (1350660-48-8) + [platinum(II)chloride((C6H4CH2N(H)(C2H5)2)2PC6H3C(CH3)2OC6H3P(C6H4CH2N(H)(C2H5)2)2)2](chloride)((SO3C6H2(CH2)(OC2H4OC2H5))4)2

Guidance literature:

In d⁽⁴⁾-methanol; byproducts: NaOTf; soln. of Pt complex (1 equiv.) and A-C stirred for 3 h at room temp., kept for 16 h at 20°C, 20 h at 60°C; various product ratio for various conditions;

DOI:10.1002/ejic.201100809

upstream raw materials:

diacetonitriledichloridopalladium(II)