Bis(acetonitrile)dichloroplatinum

Base Information

• Chemical Name: Bis(acetonitrile)dichloroplatinum
• CAS No.: 21264-32-4
• Molecular Formula: C₄H₆Cl₂N₂Pt
• Molecular Weight: 348.091
• NSC Number: 163004
• Mol file: 21264-32-4.mol

Synonyms:Bis(acetonitrile)dichloroplatinum;EINECS 237-619-2;NSC163004;NSC-163004

Chemical Property of Bis(acetonitrile)dichloroplatinum

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 0
• Exact Mass: 346.955598
• Heavy Atom Count: 9
• Complexity: 94.2

Purity/Quality:

99%min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: CC#N.CC#N.Cl[Pt]Cl

Technology Process of Bis(acetonitrile)dichloroplatinum

There total 26 articles about Bis(acetonitrile)dichloroplatinum which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

acetonitrile (75-05-8,26809-02-9) + platinum(II) chloride (10025-65-7) → bis(acetonitrile)dichloroplatinum(II) (13869-38-0,21264-32-4,13869-42-6)

Guidance literature:

at 90 ℃; for 5h; Reflux; Inert atmosphere;

DOI:10.1039/c4cc00408f

Reference yield: 94.0%

potassium tetrachloroplatinate(II) (10025-99-7) + acetonitrile (75-05-8,26809-02-9) → bis(acetonitrile)dichloroplatinum(II) (13869-38-0,21264-32-4,13869-42-6)

Guidance literature:

In water; at 75 ℃; for 3h; Inert atmosphere;

Reference yield: 81.0%

potassium tetrachloroplatinate(II) (10025-99-7) + acetonitrile (75-05-8,26809-02-9) → trans-dichloro-bis(methyl cyanide)-platinum(II) (13869-42-6,13869-38-0,21264-32-4) + diacetonitriledichloridopalladium(II) (21264-32-4,13869-38-0,13869-42-6)

Guidance literature:

In water; stirred at room temp. for 3 days with a large excess of acetonitrile; extd.(CH2Cl2), org. soln. dried (Na2SO4, 3 h), filtered, taked to dryness, Et2O added, filtered, treated with CH3CN, trans-isomer was recovered from the glass frit after washing (Et2O), org. solns. evapd., Et2O added, filtered, dried; elem. anal.;

DOI:10.1016/S0020-1693(00)84996-8

upstream raw materials:

acetonitrile

platinum(II) chloride

[PtCl₄(MeCN)2]

methyl (triphenylphosphoranylidene)acetate

Downstream raw materials:

bis(benzonitrile)dichloroplatinum(II)

cis-dichlorobis(triphenylphosphine)platinum(II)

trans-dichloro-bis(methyl cyanide)-platinum(II)

potassium tetrachloroplatinate(II)

Refernces

• 1、 Furan, Sinas,Lork, Enno,Mebs, Stefan,Hupf, Emanuel,Beckmann, Jens. "Transmetallation of Bis(6-diphenylphosphinoacenaphth-5-yl)-Mercury and -Tributyltin with Precious Metal Chlorides". . p. 856 - 865. Retrieved 2020/05/18.
• 2、 -. "PHOSPHINE COMPOUND HAVING PERFLUORO GROUP, AND COMPLEX BETWEEN METAL AND PHOSPHINE HAVING PERFLUORO GROUP". Paragraph 0252-0254. . Retrieved 2018/10/16.