[PhC(N-SiMe₃)(N'-myrtanyl)2Ni(Py)2]

Base Information

• Chemical Name: [PhC(N-SiMe₃)(N'-myrtanyl)2Ni(Py)2]
• CAS No.: 861909-17-3
• Molecular Formula: C₅₀H₇₂N₆NiSi₂
• Molecular Weight: 872.023

Synonyms:

Chemical Property of [PhC(N-SiMe₃)(N'-myrtanyl)2Ni(Py)2]

Chemical Property:

Purity/Quality:

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Technology Process of [PhC(N-SiMe₃)(N'-myrtanyl)2Ni(Py)2]

There total 2 articles about [PhC(N-SiMe₃)(N'-myrtanyl)2Ni(Py)2] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 23.0%

pyridine (110-86-1) + dimethyl(tetramethylethylenediamine)nickel(II) + Si(CH3)3NHCC6H5N(CH2C9H15) → [PhC(N-SiMe3)(N'-myrtanyl)2Ni(Py)2] (861909-17-3)

Guidance literature:

In toluene; byproducts: CH4; inert atm.; complex was dissolved in a cooled (-70°C) soln. mixt.of toluene:pyridine (3:1), reacted with a toluene-soln. of amidine, the mixt. was warmed to -20°C, stirred for 15 min at this temp., the n for 3 h at room temp.; repeated washed of ppt. with cold toluene, recrystd. at -30°C for2 weeks;

DOI:10.1016/j.jorganchem.2005.04.007

Reference yield:

pyridine (110-86-1) + [Ni(2,4-pentanedionate)2(N,N,N',N'-tetramethylethylenediamine)] + [PhC(N-SiMe3)(N'-myrtanyl)Li(TMEDA)] → [PhC(N-SiMe3)(N'-myrtanyl)2Ni(Py)2] (861909-17-3)

Guidance literature:

In diethyl ether; byproducts: Li(acetylacetonate)2, TMEDA; inert atm.; to a well-stirred soln. of Ni-complex in diethyl ether was added Li-compound, the mixt. was stirred for 10 h at room temp., filtered, evapd., washed with toluene, dried in vac., stirred in hexane-pyridinefor 1 h; cooled at -40°C for two weeks; crystals were filtered, dried under vac.; elem. anal.;

DOI:10.1016/j.jorganchem.2005.04.007

upstream raw materials:

pyridine

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