Diiodo(diphenyl)stannane

Base Information

• Chemical Name: Diiodo(diphenyl)stannane
• CAS No.: 14532-06-0
• Molecular Formula: C12H10I2Sn
• Molecular Weight: 526.73
• DSSTox Substance ID: DTXSID60392433
• Mol file: 14532-06-0.mol

Synonyms:diiodo(diphenyl)stannane;14532-06-0;Stannane, diiododiphenyl-;diphenyldiiodostannane;DIIODODIPHENYLTIN;DTXSID60392433;FPXDFNHYWPHJOJ-UHFFFAOYSA-L;AKOS024432876

Chemical Property of Diiodo(diphenyl)stannane

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 2
• Exact Mass: 527.78940
• Heavy Atom Count: 15
• Complexity: 174

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)[Sn](C2=CC=CC=C2)(I)I

Technology Process of Diiodo(diphenyl)stannane

There total 10 articles about Diiodo(diphenyl)stannane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

ammonium iodide + [Ph2SnO]n → diphenyltin diiodide (14532-06-0)

Guidance literature:

In 1,4-dioxane; water; Sn compd. suspended in 1,4-dioxane; satd. aq. soln. of NH4I added; heated under reflux until all of the Sn compd. had dissolved (12 h); solvent removed in vac.; extd. with CHCl3; org. extracts dried (Na2SO4);solvent removed; recrystd. from CHCl3-hexane;

DOI:10.1016/S0022-328X(02)01705-9

Reference yield: 76.0%

[1]naphthyl-triphenyl stannane (81134-67-0) + iodine (7553-56-2,12190-71-5,8031-47-8) → diphenyltin diiodide (14532-06-0)

Guidance literature:

In tetrachloromethane; byproducts: naphthyl iodide; react. of I2 with tin compd. soln. (molar ratio 2:1), 70°C, 1h;

Reference yield: 70.0%

iodine (7553-56-2,12190-71-5,8031-47-8) + di-[1]naphthyl-diphenyl stannane (81134-68-1) → diphenyltin diiodide (14532-06-0)

Guidance literature:

In tetrachloromethane; byproducts: naphthyl iodide; react. of I2 with tin compd. soln. (molar ratio 2:1), 70°C, 1h;

upstream raw materials:

[1]naphthyl-triphenyl stannane

iodine

di-[1]naphthyl-diphenyl stannane

tetraphenyltin(IV)

Downstream raw materials:

dimethyldiphenyltin

diphenyl-di-n-propyltin(IV)

dioctyldiphenylstannane

(C₆H₅)2Sn(C₉H₁₉)2