Benzene, 1,1',1''-[(dodecylthio)methylidyne]tris-

Base Information

• Chemical Name: Benzene, 1,1',1''-[(dodecylthio)methylidyne]tris-
• CAS No.: 145544-33-8
• Molecular Formula: C31H40S
• Molecular Weight: 444.725
• Mol file: 145544-33-8.mol

Synonyms:

Chemical Property of Benzene, 1,1',1''-[(dodecylthio)methylidyne]tris-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Benzene, 1,1',1''-[(dodecylthio)methylidyne]tris-

There total 3 articles about Benzene, 1,1',1''-[(dodecylthio)methylidyne]tris- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

triphenylmethyl alcohol (76-84-6) + 1-dodecylthiol (112-55-0) → dodecyl triphenylmethyl sulfide (145544-33-8)

Guidance literature:

With trifluoroacetic acid; In chloroform; at 20 ℃; for 3.5h; Inert atmosphere;

DOI:10.1002/chem.202001315

Reference yield: 91.0%

triphenylmethyl alcohol (76-84-6) + S-dodecyl ethanethioate (10478-23-6) → dodecyl triphenylmethyl sulfide (145544-33-8)

Guidance literature:

hydrophobic polystyrene-supported sulfonic acid; In water; for 48h; Heating;

DOI:10.1021/ol026906m

Reference yield: 57.0%

triphenylmethanethiol (3695-77-0) + 1-dodecylbromide (143-15-7) → dodecyl triphenylmethyl sulfide (145544-33-8)

Guidance literature:

With sodium hydride; In tetrahydrofuran; Heating;

DOI:10.1016/S0040-4020(99)00836-4

upstream raw materials:

triphenylmethanethiol

1-dodecylbromide

triphenylmethyl alcohol

1-dodecylthiol

Refernces

• 1、 Kim, Youngchan,Kanemoto, Kazuya,Shimomori, Ken,Hosoya, Takamitsu,Yoshida, Suguru. "Functionalization of a Single C?F Bond of Trifluoromethylarenes Assisted by an ortho-Silyl Group Using a Trityl-Based All-in-One Reagent with Ytterbium Triflate Catalyst". supporting information. p. 6136 - 6140. Retrieved 2020/05/20.
• 2、 Kobayashi, Shu,Iimura, Shinya,Manabe, Kei. "Dehydration reactions in water. Surfactant-type bronsted acid-catalyzed dehydrative etherification, thioetherification, and dithioacetalization in water". . p. 10 - 11. Retrieved 2007/10/03.