10478-23-6Relevant academic research and scientific papers
Modified Molybdenum Carbonyl Species; Excellent Reagents for the Desulphurization of Thiols
Alper, Howard,Blais, Claude
, p. 169 - 170 (1980)
Thiols can be desulfurized in good yields by treatment with molybdenum hexacarbonyl either in acetic acid or when pre-adsorbed on to silica.
Preparation of (Z)-1-fluoro-1-alkenyl carboxylates, carbonates and carbamates through chromium mediated transformation of dibromofluoromethylcarbinyl esters and the reactivity as double acyl group donors
Saito, Akio,Tojo, Manabu,Yanai, Hikaru,Wada, Fukiko,Nakagawa, Muga,Okada, Midori,Sato, Azusa,Okatani, Rieko,Taguchi, Takeo
scheme or table, p. 38 - 51 (2012/02/04)
CrCl2/Mn-mediated transformation of various dibromofluoromethylcarbinyl esters including carboxylates, carbonates and carbamates provided 1-fluoro-1-alkenyl esters via [2,3]-sigmatropic rearrangement of ester group. Reaction proceeded by using CrCl2/Mn system under mild conditions (in THF at room temperature) to give 1-fluoro-1-alkenyl esters in good yield with an excellent Z selective manner. 1-Fluoro-1-alkenyl ester thus obtained acts as a double acyl donor in the reaction with necleophiles such as amine, thiol, alcohol as well as bifunctional necleophiles such as ethylene diamine derivative.
