(E)-2-Fluor-3-methyl-1,3-octadien

Base Information

• Chemical Name: (E)-2-Fluor-3-methyl-1,3-octadien
• CAS No.: 75411-28-8
• Molecular Formula: C₉H₁₅F
• Molecular Weight: 142.217
• Mol file: 75411-28-8.mol

Synonyms:

Chemical Property of (E)-2-Fluor-3-methyl-1,3-octadien

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (E)-2-Fluor-3-methyl-1,3-octadien

There total 3 articles about (E)-2-Fluor-3-methyl-1,3-octadien which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

<(2-Chlor-2-fluor-1-ethylcyclopropyl)methyl>triphenylphosphonium-jodid → (E)-2-Fluor-3-methyl-1,3-octadien (75411-28-8) + (E)-2-Fluor-3-ethyl-4-phenyl-1,3-butadien (75411-29-9) + 6-Fluor-2,2,5-trimethyl-3,5-undecadien

Guidance literature:

With n-butyllithium; pivalaldehyde; Yield given. Multistep reaction. Yields of byproduct given; 1) THF, hexan, 3 h, -80 deg C, 2) THF, hexan, 0 deg C, 1 h;

DOI:10.1002/hlca.19800630514

Reference yield:

n-butyllithium (109-72-8,29786-93-4) + <(2-Chlor-2-fluor-1-ethylcyclopropyl)methyl>triphenylphosphonium-jodid → (E)-2-Fluor-3-methyl-1,3-octadien (75411-28-8) + (E)-2-Fluor-3-ethyl-4-phenyl-1,3-butadien (75411-29-9) + 6-Fluor-2,2,5-trimethyl-3,5-undecadien

Guidance literature:

With pivalaldehyde; Yield given. Multistep reaction. Yields of byproduct given; 1) THF, hexan, 3 h, -80 deg C, 2) THF, hexan, 0 deg C, 1 h;

DOI:10.1002/hlca.19800630514

Reference yield:

pivalaldehyde (630-19-3) + <(2-Chlor-2-fluor-1-ethylcyclopropyl)methyl>triphenylphosphonium-jodid → (E)-2-Fluor-3-methyl-1,3-octadien (75411-28-8) + (E)-2-Fluor-3-ethyl-4-phenyl-1,3-butadien (75411-29-9) + 6-Fluor-2,2,5-trimethyl-3,5-undecadien

Guidance literature:

With n-butyllithium; Yield given. Multistep reaction. Yields of byproduct given; 1) THF, hexan, 3 h, -80 deg C, 2) THF, hexan, 0 deg C, 1 h;

DOI:10.1002/hlca.19800630514

upstream raw materials:

n-butyllithium

pivalaldehyde

Refernces