7,7-Dimethylbicyclo[4.1.0]heptane

Base Information

• Chemical Name: 7,7-Dimethylbicyclo[4.1.0]heptane
• CAS No.: 1460-19-1
• Molecular Formula: C9H16
• Molecular Weight: 124.226
• DSSTox Substance ID: DTXSID801300984
• Mol file: 1460-19-1.mol

Synonyms:7,7-dimethylbicyclo[4.1.0]heptane;7,7-dimethylnorcarane;1460-19-1;DTXSID801300984;7,7-dimethyl-bicyclo[4.1.0]heptane

Chemical Property of 7,7-Dimethylbicyclo[4.1.0]heptane

Chemical Property:

• XLogP3: 3.6
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 124.125200510
• Heavy Atom Count: 9
• Complexity: 110

Purity/Quality:

95% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC1(C2C1CCCC2)C

Technology Process of 7,7-Dimethylbicyclo[4.1.0]heptane

There total 1 articles about 7,7-Dimethylbicyclo[4.1.0]heptane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 59.0%

2,2-diiodopropane (630-13-7) + cyclohexene (110-83-8) → 7,7-dimethylbicyclo[4.1.0]heptane (1460-19-1)

Guidance literature:

With diethylzinc; In cyclohexane; for 120h; Ambient temperature;

Reference yield:

7,7-dimethylbicyclo[4.1.0]heptane (1460-19-1) → (1-methylethyl)-cyclohexane (696-29-7) + 1,1-Dimethylcycloheptan (13151-49-0)

Guidance literature:

With hydrogen; palladium on activated charcoal; In cyclohexane; at 50 ℃; for 75h; under 110326 Torr; Product distribution; the formed products are detected with gas chromatography;

Reference yield:

7,7-dimethylbicyclo[4.1.0]heptane (1460-19-1) → (1-methylethyl)-cyclohexane (696-29-7)

Guidance literature:

In various solvent(s); at 130 ℃; for 12h;

DOI:10.1246/bcsj.78.1868

upstream raw materials:

2,2-diiodopropane

cyclohexene

Downstream raw materials:

(1-methylethyl)-cyclohexane

1,1-Dimethylcycloheptan

1-isopropylcyclohexene