Magnesium bis(2-methylpropan-2-ide)

Base Information

• Chemical Name: Magnesium bis(2-methylpropan-2-ide)
• CAS No.: 14627-81-7
• Molecular Formula: C8H18Mg
• Molecular Weight: 138.536
• DSSTox Substance ID: DTXSID40562197
• Mol file: 14627-81-7.mol

Synonyms:Magnesium bis(2-methylpropan-2-ide);DTXSID40562197;14627-81-7

Chemical Property of Magnesium bis(2-methylpropan-2-ide)

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 0
• Exact Mass: 138.1258923
• Heavy Atom Count: 9
• Complexity: 4.8

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C[C-](C)C.C[C-](C)C.[Mg+2]

Technology Process of Magnesium bis(2-methylpropan-2-ide)

There total 1 articles about Magnesium bis(2-methylpropan-2-ide) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

tertiary butyl chloride (507-20-0) → tert-butylmagnesium chloride (677-22-5) + di-tert-butylmagnesium (14627-81-7)

Guidance literature:

With diethyl ether; magnesium; In toluene; Ambient temperature; solvatation of Grignard reagent by diethyl ether;

DOI:10.1016/0022-328X(96)06423-6

Reference yield: 95.0%

3-Bromopyridine (626-55-1,163928-56-1) + triisopropylsilyl trifluoromethanesulfonate (80522-42-5) + di-tert-butylmagnesium (14627-81-7) → C18H34BrNSi

Guidance literature:

3-Bromopyridine; triisopropylsilyl trifluoromethanesulfonate; In dichloromethane; at 20 ℃; for 0.25h; Inert atmosphere;

di-tert-butylmagnesium; In 1,4-dioxane; diethyl ether; dichloromethane; at -85 ℃; for 16h; Inert atmosphere;

DOI:10.1055/s-0036-1589025

Reference yield: 89.0%

3-Ethynylpyridine (2510-23-8) + triisopropylsilyl trifluoromethanesulfonate (80522-42-5) + di-tert-butylmagnesium (14627-81-7) → C20H35NSi

Guidance literature:

3-Ethynylpyridine; triisopropylsilyl trifluoromethanesulfonate; In dichloromethane; at 20 ℃; for 0.25h; Inert atmosphere;

di-tert-butylmagnesium; In 1,4-dioxane; diethyl ether; dichloromethane; at -85 ℃; for 16h; Inert atmosphere;

DOI:10.1055/s-0036-1589025

upstream raw materials:

tertiary butyl chloride

Downstream raw materials:

2,2,4,4-tetramethyl-3-pentanol

tri-tert-butylcarbinol

(1S)-2,2-dimethyl-1-phenyl-1-propanol

2,2-dimethyl-1-phenyl-1-propanol