Ethylium, 1,1-dimethyl-

Base Information

• Chemical Name: Ethylium, 1,1-dimethyl-
• CAS No.: 14804-25-2
• Molecular Formula: C4H9
• Molecular Weight: 57.1155
• Mol file: 14804-25-2.mol

Synonyms:

Chemical Property of Ethylium, 1,1-dimethyl-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Ethylium, 1,1-dimethyl-

There total 12 articles about Ethylium, 1,1-dimethyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

tertiary butyl chloride (507-20-0) + benzylium cation (6711-19-9) → tert-butyl cation (14804-25-2) + benzyl chloride (100-44-7)

Guidance literature:

With methane; In gaseous matrix; at 30 ℃; Thermodynamic data; Equilibrium constant; Rate constant; various temperature (300-640 K); ΔH₄⁰, ΔS₄⁰, ΔG₄⁰; effect of side reactions;

Reference yield:

tert-butylium; compound with trichloromethane (1:1) (96164-30-6) → chloroform (67-66-3,8013-54-5) + tert-butyl cation (14804-25-2)

Guidance literature:

In gaseous matrix; under 4 Torr; Thermodynamic data; Equilibrium constant; several temperature; ΔH, ΔS, ΔG;

DOI:10.1021/ja00299a002

Reference yield:

Isobutane (75-28-5,40921-86-6) + exo-2-bromonorbornane (2534-77-2,2566-14-5,13237-87-1,29342-65-2,67815-05-8,67815-06-9,67844-23-9,76420-01-4,130404-12-5) → tert-butyl cation (14804-25-2) + norbornene (279-23-2)

Guidance literature:

With aluminum tri-bromide; In dichloromethane; at -80 ℃; Thermodynamic data; equilibrium; enthalpy change; ΔG;

DOI:10.1021/j100353a057

upstream raw materials:

Isobutane

tert-butyl-d9 cation

exo-2-bromonorbornane

dimethylsilanylium

Downstream raw materials:

Isobutane

tert-amyl cation

dimethylsilanylium

tert-butyl-d9 cation