4-(5-Methylfuran-2-yl)thiazol-2-amine

Base Information

• Chemical Name: 4-(5-Methylfuran-2-yl)thiazol-2-amine
• CAS No.: 1634-46-4
• Molecular Formula: C₈H₈N₂OS
• Molecular Weight: 180.23
• Hs Code.: 2934100090
• European Community (EC) Number: 821-533-2
• DSSTox Substance ID: DTXSID40366576
• Wikidata: Q82151847
• Mol file: 1634-46-4.mol

Synonyms:1634-46-4;4-(5-methylfuran-2-yl)thiazol-2-amine;4-(5-methylfuran-2-yl)-1,3-thiazol-2-amine;4-(5-Methyl-furan-2-yl)-thiazol-2-ylamine;4-(5-methyl-2-furyl)-1,3-thiazol-2-amine;2-Thiazolamine, 4-(5-methyl-2-furanyl)-;SCHEMBL127716;DTXSID40366576;HIBFSFCLIHHSJZ-UHFFFAOYSA-N;BAA63446;MFCD00503492;AKOS000122390;SB61027;WAY-345113;AC-37185;WS-02060;FT-0678709;EN300-08762;D97328;A882575;Z96092263;4-(5-methyl-2-furyl)-1,3-thiazol-2-amine, AldrichCPR;F1908-0040

Chemical Property of 4-(5-Methylfuran-2-yl)thiazol-2-amine

Chemical Property:

• Vapor Pressure: 0.000166mmHg at 25°C
• Boiling Point: 330.5°Cat760mmHg
• Flash Point: 153.7°C
• PSA: 80.29000
• Density: 1.298g/cm³
• LogP: 2.87490
• Storage Temp.: Keep in dark place,Sealed in dry,Room Temperature
• XLogP3: 1.8
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 1
• Exact Mass: 180.03573406
• Heavy Atom Count: 12
• Complexity: 167

Purity/Quality:

97% ^*data from raw suppliers

4-(5-methylfuran-2-yl)-1,3-thiazol-2-amine ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC1=CC=C(O1)C2=CSC(=N2)N

Technology Process of 4-(5-Methylfuran-2-yl)thiazol-2-amine

There total 2 articles about 4-(5-Methylfuran-2-yl)thiazol-2-amine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 29.0%

2-bromo-1-(5-methyl-furan-2-yl)ethanone (1634-53-3) + thiourea (17356-08-0) → 4-(5-methylfuran-2-yl)thiazol-2-amine (1634-46-4)

Guidance literature:

In ethanol; at 80 ℃; for 2h;

Reference yield:

2-acetyl-5-methylfuran (1193-79-9) → 4-(5-methylfuran-2-yl)thiazol-2-amine (1634-46-4)

Guidance literature:

Multi-step reaction with 2 steps

1: bromine / 1,4-dioxane; diethyl ether / 0 - 30 °C

2: ethanol / 2 h / 80 °C

With bromine; In 1,4-dioxane; diethyl ether; ethanol;

upstream raw materials:

2-bromo-1-(5-methyl-furan-2-yl)ethanone

thiourea

2-acetyl-5-methylfuran

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