Borane, bis(pentafluorophenyl)phenyl-

Base Information

Chemical Name:Borane, bis(pentafluorophenyl)phenyl-
CAS No.:148892-98-2
Molecular Formula:C18H5BF10
Molecular Weight:422.033
Hs Code.:
DSSTox Substance ID:DTXSID30462511
Nikkaji Number:J1.038.046D
Wikidata:Q82287056

Synonyms:Borane, bis(pentafluorophenyl)phenyl-;148892-98-2;Borane, bis(2,3,4,5,6-pentafluorophenyl)phenyl-;bis(2,3,4,5,6-pentafluorophenyl)-phenylborane;PhB(C6F5)2;SCHEMBL619771;DTXSID30462511

Suppliers and Price of Borane, bis(pentafluorophenyl)phenyl-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 6 raw suppliers

Chemical Property of Borane, bis(pentafluorophenyl)phenyl-

Chemical Property:

PSA：0.00000
LogP:3.59380
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:10
Rotatable Bond Count:3
Exact Mass:422.0324619
Heavy Atom Count:29
Complexity:479

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:B(C1=CC=CC=C1)(C2=C(C(=C(C(=C2F)F)F)F)F)C3=C(C(=C(C(=C3F)F)F)F)F

Technology Process of Borane, bis(pentafluorophenyl)phenyl-

There total 6 articles about Borane, bis(pentafluorophenyl)phenyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 56.0%

: 873-51-8
phenylborondichloride

: 148892-98-2
phenylbis(pentafluorophenyl)borane

Guidance literature:: In toluene;
DOI:10.1016/S0022-328X(03)00588-6

Reference yield: 56.0%

: [pentafluorophenylcopper]4(η2-toluene)2

: 873-51-8
phenylborondichloride

: 148892-98-2
phenylbis(pentafluorophenyl)borane

Guidance literature:: In toluene; under N2; soln. of PhBCl2 (0.5 equiv) in toluene added dropwise to soln.of (Cu(C6F5))4(η2-toluene)2 in toluene at -78 °C; mixt. stir red at -78 °C for 1 h, allowed to slowly warm to room temp., and stirred for addnl. 12 h; react. mixt. filtered through fritted glass disk and washed twice with toluene; all volatiles removed under vac.; crude product purified by crystn. from hexanes at -37 °C;
DOI:10.1016/S0022-328X(03)00588-6

Reference yield: 32.0%

: 873-51-8
phenylborondichloride

: 1076-44-4
pentafluorophenyl lithium

: 148892-98-2
phenylbis(pentafluorophenyl)borane

Guidance literature:: In pentane; byproducts: LiCl; Schlenk techniques; B-compd. soln. addn. (syringe) to stirred org. compd. suspn. at -78°C, mixt. stirring (12 h, warming to 25°C), Li-salt ppt. filtration off, filtrate evapn.; residue recrystn. (pentane, -30°C), sublimation; elem. anal.;
DOI:10.1021/ja972912f