2-Undecyl-1,3-dioxolane

Base Information

• Chemical Name: 2-Undecyl-1,3-dioxolane
• CAS No.: 5735-88-6
• Molecular Formula: C14H28O2
• Molecular Weight: 228.375
• NSC Number: 48573
• DSSTox Substance ID: DTXSID10287002
• Nikkaji Number: J1.255.407I
• Wikidata: Q82022892
• Mol file: 5735-88-6.mol

Synonyms:2-undecyl-1,3-dioxolane;5735-88-6;1,3-Dioxolane,2-undecyl-;NSC48573;2-n-undecyl-1,3 dioxolane;SCHEMBL1668988;DTXSID10287002;BKFFGALSQITQAW-UHFFFAOYSA-N;NSC-48573

Chemical Property of 2-Undecyl-1,3-dioxolane

Chemical Property:

• Vapor Pressure: 0.00651mmHg at 25°C
• Refractive Index: 1.442
• Boiling Point: 280.2 °C at 760 mmHg
• Flash Point: 112.2 °C
• PSA: 18.46000
• Density: 0.888 g/cm³
• LogP: 4.28020
• XLogP3: 5.5
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 10
• Exact Mass: 228.208930132
• Heavy Atom Count: 16
• Complexity: 142

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCCCCCCCCCC1OCCO1

Technology Process of 2-Undecyl-1,3-dioxolane

There total 6 articles about 2-Undecyl-1,3-dioxolane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

1-dodecyl alcohol (112-53-8) + ethylene glycol (107-21-1) → 2-undecanyl-1,3-dioxolane (5735-88-6)

Guidance literature:

With dimethyl sulfoxide; [ReOCl₃(PPh₃)₂]; In toluene; for 23h; Heating;

DOI:10.1021/ol990755e

Reference yield: 66.0%

1-Bromononane (693-58-3) + (2-(1,3-dioxolan-2-yl)ethyl)zinc(II) bromide → 2-undecanyl-1,3-dioxolane (5735-88-6)

Guidance literature:

With 1,3-bis[2,6-diisopropylphenyl]imidazolium chloride; tris(dibenzylideneacetone)dipalladium ⁽⁰⁾; In tetrahydrofuran; 1-methyl-pyrrolidin-2-one; at 20 ℃; for 24h;

DOI:10.1016/j.tet.2005.07.101

Reference yield:

Dodecanal (112-54-9) + ethylene glycol (107-21-1) → 2-undecanyl-1,3-dioxolane (5735-88-6) + (1-(2-hydroxyethoxy)dodecan-1-ol)

Guidance literature:

With phenyl sulfonic grafted on activated charcoal; In 2-methyltetrahydrofuran; toluene; at 60 ℃; for 2h; Reagent/catalyst; Kinetics;

DOI:10.1016/j.apcata.2020.117543

upstream raw materials:

1-Bromononane

1-dodecyl alcohol

ethylene glycol

2-pentyl-1,3-dioxolane

Downstream raw materials:

ethylene glycol monolaurate

Dodecanal

1-dodecyl alcohol

(R)-1'-<((2''S,3''S)-3''-hexyl-4''-oxo-2''-oxetanyl)methyl>dodecyl (S)-N-formylleucinate