2-Nitrophenazine

Base Information

• Chemical Name: 2-Nitrophenazine
• CAS No.: 3442-62-4
• Molecular Formula: C12H7 N3 O2
• Molecular Weight: 225.206
• Hs Code.: 2933990090
• DSSTox Substance ID: DTXSID30187999
• Nikkaji Number: J1.393.097J
• Wikidata: Q83059765
• ChEMBL ID: CHEMBL165311
• Mol file: 3442-62-4.mol

Synonyms:2-Nitrophenazine;Phenazine, 2-nitro-;3442-62-4;CCRIS 3015;BRN 0199833;2-Nitro-phenazine;CHEMBL165311;DTXSID30187999;LS-103021

Chemical Property of 2-Nitrophenazine

Chemical Property:

• Vapor Pressure: 8.7E-08mmHg at 25°C
• Boiling Point: 447.7°C at 760 mmHg
• Flash Point: 224.6°C
• PSA: 71.60000
• Density: 1.444g/cm³
• LogP: 3.21440
• XLogP3: 2.5
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 0
• Exact Mass: 225.053826475
• Heavy Atom Count: 17
• Complexity: 305

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C2C(=C1)N=C3C=CC(=CC3=N2)[N+](=O)[O-]

Technology Process of 2-Nitrophenazine

There total 4 articles about 2-Nitrophenazine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 58.0%

2,4-Dinitrodiphenylacetamide (106038-76-0) → 2-nitrophenazine (3442-62-4) + 2-nitrophenazine 10-oxide (2876-33-7) + 4-Nitro-2-nitrosodiphenylamine (145490-69-3)

Guidance literature:

With 2,6-di-tert-butylphenol; In benzene; for 0.5h; Irradiation;

Reference yield:

Phenazin (92-82-0) → 1,4-dihydroxyphenazine (1790-81-4) + phenazin-1-ol (528-71-2) + 1-nitrophenazine (2876-24-6) + 2-nitrophenazine (3442-62-4)

Guidance literature:

With water; Nitrate; Kinetics; Irradiation;

DOI:10.1016/S0045-6535(98)00188-X

Reference yield:

Phenazin-mono-N-Oxyd (304-81-4) → 2-nitrophenazine (3442-62-4)

Guidance literature:

Multi-step reaction with 2 steps

1: H₂SO₄; aqueous HNO₃

2: N,N-dimethyl-aniline; acetic acid anhydride

With sulfuric acid; nitric acid; acetic anhydride; N,N-dimethyl-aniline;

DOI:10.1248/cpb1953.2.283

upstream raw materials:

2,4-Dinitrodiphenylacetamide

Phenazin

Phenazin-mono-N-Oxyd