187605-59-0

Basic information

• Product Name: 1(2H)-Acenaphthylenone, 2-[[2,6-bis(1-methylethyl)phenyl]imino]-
• CAS NO: 187605-59-0
• Molecular Formula: C24H23NO
• Molecular Weight: 341.453
• Mol File: 187605-59-0.mol

Chemical Properties

• CAS DataBase Reference: 1(2H)-Acenaphthylenone, 2-[[2,6-bis(1-methylethyl)phenyl]imino]-(CAS DataBase Reference)
• NIST Chemistry Reference: 1(2H)-Acenaphthylenone, 2-[[2,6-bis(1-methylethyl)phenyl]imino]-(187605-59-0)
• EPA Substance Registry System: 1(2H)-Acenaphthylenone, 2-[[2,6-bis(1-methylethyl)phenyl]imino]-(187605-59-0)

Safety Data

• Hazardous Substances Data: 187605-59-0(Hazardous Substances Data)

Upstream product

• 24544-04-5 2,6-diisopropylbenzenamine 
• 82-86-0 acenaphthene quinone 

Downstream Products

• 1393484-89-3 ClCu([N-(2,6-diisopropylphenyl)-imino]acenaphthenone) 
• 928796-18-3 (1-(2,6-diisopropylphenylimino)-2-(2,6-dimethylphenylimino)acenaphthylenylidene)NiBr₂ 
• 1443050-74-5 1-(2,6-diisopropylphenylimino)-2-(2,6-dimethylphenylimino)acenaphthylenylidene 
• 1443050-81-4 (1-(2,6-diisopropylphenylimino)-2-(2,6-diethylphenylimino)acenaphthylenylidene)NiBr₂ 
• 1443050-75-6 1-(2,6-diisopropylphenylimino)-2-(2,6-diethylphenylimino)acenaphthylenylidene 
• 1443050-76-7 1-(2,6-diisopropylphenylimino)-2-(2,4,6-trimethylphenylimino)acenaphthylenylidene 
• 1443050-77-8 1-(2,6-diisopropylphenylimino)-2-(2,6-diethyl-4-methylphenylimino)acenaphthylenylidene 
• 1613692-30-0 C₄₄H₄₀N₂O₂ 
• 1613692-29-7 C₅₀H₅₂N₂ 
• 1428247-59-9 C₂₅H₂₇NO 

Relevant articles and documents

Oligomerization of ethylene using new tridentate iron catalysts bearing α-diimine ligands with pendant S and P donors

Stoichiometric Schiff base condensations of sterically bulky primary amines with acenaphthenequinone yield isolable monoimines. In the presence of iron(II) chloride, the remaining ketone reacts with a second primary amine bearing a pendant donor atom to g

Mono- and binuclear nickel catalysts for 1-hexene polymerization

Polymerization of 1-hexene was carried out using a mononuclear (MN) catalyst and two binuclear (BN1 and BN2) α-diimine Ni-based catalysts synthesized under controlled conditions. Ethylaluminium sesquichloride (EASC) was used as an ef

Polymerization of ethylene using a series of binuclear and a mononuclear Ni (II)-based catalysts

A novel series of homo-, bi-, and mononuclear Ni(II)-based catalysts (BNCn n = 1–4, MNC4) were used for ethylene polymerization. The optimum conditions for the catalyst BNC4 (the highest catalytic activity) was obtained at

A low-symmetry nickel(II) α-diimine complex for homopolymerization of ethylene: Study of interactive effects of polymerization parameters

In this contribution, the synthesis and characterization of a non-symmetric nickel(II) α-diimine complex [(2,4,6-trimethylphenyl)imino)-((2,6-diisopropylphenyl)imino)-acenaphthene nickel(II) dibromide] have been reported as a catalyst precursor for ethyle

CATALYTIC SYSTEM FOR PREPARATION OF HIGH BRANCHED ALKANE FROM OLEFINS

The present invention discloses a catalytic system for preparing highly branched alkane from olefin, which contains novel nickel or palladium complexes. In the presence of the catalytic system, highly branched oily alkane mixture can be efficiently obtain

A thermal stable α-diimine palladium catalyst for copolymerization of ethylene with functionalized olefins

Copolymerization of polar monomers and olefins catalyzed by transition metal under mild conditions is a challenge. α-Diimine palladium complexes have great potential to catalyze the copolymerization of alkylacrylates and olefins. But they are prone to deactivation under mild conditions which limits their industrial application. A novel unsymmetrical α-diimine palladium complex with bulkier α-diimine ligand was provided in this paper. They were active in ethylene homopolymerization at 80 °C. At 50 °C they could produce ethylene/methylacrylate copolymer with moderate methylacrylate incorporation. The probable reason for the high thermal stability of these complexes was proposed.