1H-1-Benzarsepin, 1-phenyl-

Base Information

Chemical Name:1H-1-Benzarsepin, 1-phenyl-
CAS No.:154081-41-1
Molecular Formula:C16H13As
Molecular Weight:280.201
Hs Code.:
Mol file:154081-41-1.mol

Synonyms:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 1H-1-Benzarsepin, 1-phenyl-

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Technology Process of 1H-1-Benzarsepin, 1-phenyl-

There total 8 articles about 1H-1-Benzarsepin, 1-phenyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 154467-46-6
5-Phenyl-6-trimethylsilanyl-5H-5-arsa-benzocycloheptene

: 154081-41-1
1-phenyl-1-benzoarsepine

Guidance literature:: With tetrabutyl ammonium fluoride; In tetrahydrofuran; for 12h; Ambient temperature;
DOI:10.1039/c39930001817

Reference yield: 75.0%

: 154081-40-0
1-phenyl-1-benzarsepine 1-oxide

: 154081-41-1
1-phenyl-1-benzoarsepine

Guidance literature:: With trichlorosilane;

Reference yield:

: 7345-79-1
2-bromocinnamic acid

: 154081-41-1
1-phenyl-1-benzoarsepine

Guidance literature:: Multi-step reaction with 6 steps

1.1: 95 percent / Br₂ / CCl₄ / 2 h / Heating

2.1: 95 percent / NaHCO₃ / acetone / 12 h / Heating

3.1: 88 percent / PdCl₂(PPh₃)2; Et₂NH; CuI / 3 h / 0 °C

4.1: DIBAL-H / hexane / 50 h / 20 °C

4.2: NBS / 6 h / -20 °C

5.1: t-BuLi / diethyl ether / -80 - -20 °C

5.2: 28 percent / diethyl ether / 6.5 h / -80 - 20 °C

6.1: 83 percent / aq. TBAF / tetrahydrofuran / 1.5 h

With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; tetrabutyl ammonium fluoride; bromine; tert.-butyl lithium; diisobutylaluminium hydride; sodium hydrogencarbonate; diethylamine; In tetrahydrofuran; tetrachloromethane; diethyl ether; hexane; acetone; 1.1: Bromination / 2.1: Decarboxylation / 3.1: Alkylation / 4.1: Reduction / 4.2: Bromination / 5.1: Metallation / 5.2: Cyclization / 6.1: Reduction;
DOI:10.1248/cpb.47.1108