Iron, tricarbonyldiiodo(triphenylphosphine)-

Base Information

• Chemical Name: Iron, tricarbonyldiiodo(triphenylphosphine)-
• CAS No.: 15530-61-7
• Molecular Formula: C₂₁H₁₅FeI₂O₃P
• Molecular Weight: 655.978
• Mol file: 15530-61-7.mol

Synonyms:

Chemical Property of Iron, tricarbonyldiiodo(triphenylphosphine)-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Iron, tricarbonyldiiodo(triphenylphosphine)-

There total 2 articles about Iron, tricarbonyldiiodo(triphenylphosphine)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

diiodotetracarbonyliron(II) (15616-56-5,14911-55-8,14878-30-9) + triphenylphosphine (603-35-0) → mer-tricarbonyldiiodo(triphenylphosphane)iron(II) (15530-61-7,51744-71-9,62075-68-7)

Guidance literature:

In hexane; (N2), in the dark; soln. of PPh3 in hexane added to soln. of iron complex in hexane, mixt. stirred at room temp.for 1 h; J. Inorg. Nucl. Chem. 1966, 28, 511-520; J. Organomet. Chem. 1977, 125, 231-252; J. Organomet. Chem. 2006, 691, 3881-3888; evapn. under vac., residue washed with hexane, dried under vac.; elem. anal.;

DOI:10.1021/ic9017882

Reference yield: 93.0%

diiodotetracarbonyliron(II) (15616-56-5,14911-55-8,14878-30-9) + triphenylphosphine (603-35-0) → FeI2(CO)3PPh3 (15530-61-7,51744-71-9,62075-68-7)

Guidance literature:

In diethyl ether; -40°C to room temp., 1:1 or 1:2 ratio of educts; recrystn. from acetone/water;

DOI:10.1039/DT9730002103 DOI:10.1016/0022-1902(66)80332-9 DOI:10.1039/J19700000634

Reference yield: 92.7%

FeI2(CO)3PPh3 (15530-61-7,51744-71-9,62075-68-7) + Benzene-1,2-dithiol (17534-15-5) → bis[(triphenylphosphine)dicarbonyl(o-benzenedithiolate)iron(II)] (87350-39-8)

Guidance literature:

With butyllithium; In tetrahydrofuran; byproducts: LiI, CO; under N2, reacting a soln. of organic compound with butyllithium at -78°C, warming to room temperature, addn. of reaction mixture to a soln. of Fe-complex, stirring for 1 h; distn., dissolving residue in CH2Cl2, filtn., washing (Et2O), drying (vac.), elem. anal.;

upstream raw materials:

diiodotetracarbonyliron(II)

triphenylphosphine

Downstream raw materials:

tricarbonyl bis(triphenylphosphine) iron

Fe(CO)2(P(C₆H₅)3){P(OCH₃)3}2

bis[(triphenylphosphine)dicarbonyl(o-benzenedithiolate)iron(II)]

[(triphenylphosphine)(carbonyl)bis(o-methylthiobenzenethiolate)iron(II)]