4-bromo-2-{(E)-[(4-methoxyphenyl)imino]methyl}phenol

Base Information

Chemical Name:4-bromo-2-{(E)-[(4-methoxyphenyl)imino]methyl}phenol
CAS No.:20772-73-0
Molecular Formula:C14H12 Br N O2
Molecular Weight:306.159
Hs Code.:
NSC Number:201826
DSSTox Substance ID:DTXSID90419869
Wikidata:Q82231084
ChEMBL ID:CHEMBL2236407

Synonyms:NSC201826;4-bromo-2-{(E)-[(4-methoxyphenyl)imino]methyl}phenol;CHEMBL2236407;20772-73-0;4-bromo-2-{[(4-methoxyphenyl)imino]methyl}phenol;SCHEMBL12416699;DTXSID90419869;BDBM50486322;MFCD00115297;STK084315;AKOS003407871;NSC-201826;BS-10509;CS-0338515;4-bromo-2-[(4-methoxyphenylimino)methyl]phenol;(E)-4-bromo-2-(((4-methoxyphenyl)imino)methyl)phenol;4-BROMO-2-((4-METHOXY-PHENYLIMINO)-METHYL)-PHENOL;1227260-60-7

Suppliers and Price of 4-bromo-2-{(E)-[(4-methoxyphenyl)imino]methyl}phenol

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 3 raw suppliers

Chemical Property of 4-bromo-2-{(E)-[(4-methoxyphenyl)imino]methyl}phenol

Chemical Property:

Vapor Pressure:4.79E-06mmHg at 25°C
Boiling Point:382.3°C at 760 mmHg
Flash Point:185°C
Density:1.607g/cm³
XLogP3:3.8
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:3
Exact Mass:305.00514
Heavy Atom Count:18
Complexity:277

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:COC1=CC=C(C=C1)N=CC2=C(C=CC(=C2)Br)O

Technology Process of 4-bromo-2-{(E)-[(4-methoxyphenyl)imino]methyl}phenol

There total 2 articles about 4-bromo-2-{(E)-[(4-methoxyphenyl)imino]methyl}phenol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 104-94-9
4-methoxy-aniline

: 1761-61-1
5-bromosalicyclaldehyde

: 20772-73-0
5-bromo-salicylidene-4-methoxyaniline

Guidance literature:: With ethanol;
DOI:10.1021/ja01329a049

Reference yield:

: 90-02-8
salicylaldehyde

: 20772-73-0
5-bromo-salicylidene-4-methoxyaniline

Guidance literature:: Multi-step reaction with 2 steps

1: tetrachloromethane; bromine

2: ethanol

With tetrachloromethane; ethanol; bromine;
DOI:10.1021/ja01329a049

Reference yield: 95.0%

: 1191-99-7,75454-45-4
2,3-dihydro-2H-furan

: 20772-73-0
5-bromo-salicylidene-4-methoxyaniline

: 1360873-61-5
(3aS,4R,9aR)-6-bromo-N-(4-methoxyphenyl)-3,3a,4,9a-tetrahydro-2H-furo[2,3-b]chromen-4-amine

Guidance literature:: 5-bromo-salicylidene-4-methoxyaniline; With (S,2S,2'S)-1,1'-(propane-1,3-diyl)bis(2-(((S)-1-phenylethyl)carbamoyl)piperidine 1-oxide); scandium tris(trifluoromethanesulfonate); In chloroform; at 25 ℃; for 1h; Molecular sieve; Inert atmosphere;

2,3-dihydro-2H-furan; In chloroform; at -20 ℃; for 5h; optical yield given as %ee; enantioselective reaction; Inert atmosphere;
DOI:10.1002/chem.201102058