(Sixantphos)(4-cyanophenyl)bromopalladium(II)

Base Information

• Chemical Name: (Sixantphos)(4-cyanophenyl)bromopalladium(II)
• CAS No.: 335232-83-2
• Molecular Formula: C₄₅H₃₆BrNOP₂PdSi
• Molecular Weight: 883.144
• Mol file: 335232-83-2.mol

Synonyms:

Chemical Property of (Sixantphos)(4-cyanophenyl)bromopalladium(II)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (Sixantphos)(4-cyanophenyl)bromopalladium(II)

There total 1 articles about (Sixantphos)(4-cyanophenyl)bromopalladium(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

4,6-bis(diphenylphosphanyl)-10,10-dimethyl-10H-dibenzo[b,e][1,4]oxasilane (166330-11-6) + ([(o-tolyl)3P]Pd(II)(4-cyanophenyl)Br)2 (193001-39-7) → (Sixantphos)(4-cyanophenyl)bromopalladium(II) (335232-83-2)

Guidance literature:

In dichloromethane; soln. of Pd complex and ligand (molar ratio 1:2) in CH2Cl2 reacted overnight at room temp.; concd. in vac.; Et2O added; filtered; crystals dried in vac.;

DOI:10.1039/b111596k

Reference yield:

(Sixantphos)(4-cyanophenyl)bromopalladium(II) (335232-83-2) + cis-(Sixantphos)(4-cyanophenyl)bromopalladium(II) (335232-83-2) + silver trifluoromethanesulfonate (2923-28-6) → (Sixantphos)(4-cyanophenyl)palladium(II) triflate (335232-88-7)

Guidance literature:

In dichloromethane; acetonitrile; byproducts: AgBr; soln. of Pd complex (mixt. of cis- and trans-isomers) and AgOSO2CF3 (molar ratio 1:1) in CH2Cl2-MeCN stirred in the dark for 1 h; suspn. of Norit in CH2Cl2 added; stirred for 1 h; filtered; filtrate concd. under vac.; Et2O added; filtered; dried in vac.;

DOI:10.1039/b111596k

Reference yield:

(Sixantphos)(4-cyanophenyl)bromopalladium(II) (335232-83-2) + cis-(Sixantphos)(4-cyanophenyl)bromopalladium(II) (335232-83-2) + silver trifluoromethanesulfonate (2923-28-6) → (Sixantphos)(4-cyanophenyl)palladium(II) triflate (335232-88-7)

Guidance literature:

In dichloromethane; acetonitrile; byproducts: AgBr; soln. of Pd complex (mixt. of cis- and trans-isomers) and AgOSO2CF3 (molar ratio 1:1) in CH2Cl2-MeCN stirred in the dark for 1 h; suspn. of Norit in CH2Cl2 added; stirred for 1 h; filtered; filtrate concd. under vac.; Et2O added; filtered; dried in vac.;

DOI:10.1039/b111596k

upstream raw materials:

4,6-bis(diphenylphosphanyl)-10,10-dimethyl-10H-dibenzo[b,e][1,4]oxasilane

([(o-tolyl)3P]Pd(II)(4-cyanophenyl)Br)2

Downstream raw materials:

(Sixantphos)(4-cyanophenyl)palladium(II) triflate