Arsine, (1Z)-1,2-ethenediylbis[diphenyl-

Base Information

• Chemical Name: Arsine, (1Z)-1,2-ethenediylbis[diphenyl-
• CAS No.: 15924-20-6
• Molecular Formula: C26H22As2
• Molecular Weight: 484.304
• Mol file: 15924-20-6.mol

Synonyms:

Chemical Property of Arsine, (1Z)-1,2-ethenediylbis[diphenyl-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Arsine, (1Z)-1,2-ethenediylbis[diphenyl-

There total 3 articles about Arsine, (1Z)-1,2-ethenediylbis[diphenyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

cis-1,2-Dichloroethylene (156-59-2,43695-79-0) + diphenylarsane (829-83-4) → cis-1,2-vinylenebis(diphenylarsine) (15924-20-6)

Guidance literature:

diphenylarsane; With n-butyllithium; In tetrahydrofuran; hexane; at -78 ℃; for 1h;

cis-1,2-Dichloroethylene; In tetrahydrofuran; hexane; at 18.5 ℃; Further stages.;

DOI:10.1021/ja0176705

Reference yield: 78.0%

cis-1,2-Dichloroethylene (156-59-2,43695-79-0) + hexaphenylcyclohexaarsane (20738-31-2) + phenyllithium (591-51-5) → cis-1,2-vinylenebis(diphenylarsine) (15924-20-6)

Guidance literature:

hexaphenylcyclohexaarsane; phenyllithium; In tetrahydrofuran; dibutyl ether; at 20 ℃; for 2h;

cis-1,2-Dichloroethylene; at 20 ℃;

DOI:10.1039/c6dt00723f

Reference yield:

→ cis-1,2-vinylenebis(diphenylarsine) (15924-20-6)

Guidance literature:

cis-1,2-Dichlorethen, Lithiumdiphenylarsenid, THF;

DOI:10.1021/jo01268a094

upstream raw materials:

cis-1,2-Dichloroethylene

diphenylarsane

hexaphenylcyclohexaarsane

phenyllithium

Downstream raw materials:

N(CH₂CH₂CH₃)4⁽¹⁺⁾*Cr((C₆H₅)2AsCHCHAs(C₆H₅)2)Cl₄^(1-)=N(CH₂CH₂CH₃)4Cr((C₆H₅)2AsCHCHAs(C₆H₅)2)Cl₄

tetrapropylammonium [Cr(cis-Ph₂AsCHCHAsPh₂)Cl₄]

Refernces

• 1、 Tanaka, Susumu,Imoto, Hiroaki,Kato, Takuji,Naka, Kensuke. "A practical method for the generation of organoarsenic nucleophiles towards the construction of a versatile arsenic library". supporting information. p. 7937 - 7940. Retrieved 2016/06/09.