(2S)-3-(2,2-Dimethyl-1,1-diphenyl-1-silapropoxy)propane-1,2-diol

Base Information

Chemical Name:(2S)-3-(2,2-Dimethyl-1,1-diphenyl-1-silapropoxy)propane-1,2-diol
CAS No.:161469-43-8
Molecular Formula:C19H26O3Si
Molecular Weight:330.499
Hs Code.:
DSSTox Substance ID:DTXSID20445217
Nikkaji Number:J2.978.827H
Mol file:161469-43-8.mol

Synonyms:(2S)-3-(2,2-Dimethyl-1,1-diphenyl-1-silapropoxy)propane-1,2-diol;161469-43-8;SCHEMBL218117;DTXSID20445217;RYZYNNLPABISLU-INIZCTEOSA-N;O-(t-butyldiphenylsilyl)-sn-glycerol;(S)-3-(tert-Butyldiphenylsilyloxy)propane-1,2-diol

Suppliers and Price of (2S)-3-(2,2-Dimethyl-1,1-diphenyl-1-silapropoxy)propane-1,2-diol

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Total 0 raw suppliers

Chemical Property of (2S)-3-(2,2-Dimethyl-1,1-diphenyl-1-silapropoxy)propane-1,2-diol

Chemical Property:

PSA：49.69000
LogP:1.91620
Hydrogen Bond Donor Count:2
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:7
Exact Mass:330.16512122
Heavy Atom Count:23
Complexity:323

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(C)(C)[Si](C1=CC=CC=C1)(C2=CC=CC=C2)OCC(CO)O
Isomeric SMILES:CC(C)(C)[Si](C1=CC=CC=C1)(C2=CC=CC=C2)OC[C@H](CO)O

Technology Process of (2S)-3-(2,2-Dimethyl-1,1-diphenyl-1-silapropoxy)propane-1,2-diol

There total 14 articles about (2S)-3-(2,2-Dimethyl-1,1-diphenyl-1-silapropoxy)propane-1,2-diol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 1-(tert-butyl-dimethyl-silanyloxy)-3-(tert-butyl-diphenyl-silanyloxy)-propan-2-ol

: 161469-43-8
(S)-3-((tert-butyldiphenylsilyl)oxy)propane-1,2-diol

Guidance literature:: With iodine(I) bromide; In methanol; dichloromethane; for 0.25h; Ambient temperature;

Reference yield: 87.0%

: Acetic acid (R)-3-(tert-butyl-diphenyl-silanyloxy)-2-hydroxy-1-p-tolylsulfanyl-propyl ester

: 161469-43-8
(S)-3-((tert-butyldiphenylsilyl)oxy)propane-1,2-diol

Guidance literature:: With lithium borohydride; In tetrahydrofuran; Ambient temperature;
DOI:10.1080/00397919808004924

Reference yield: 77.0%

: 1341195-50-3
2-acetyl-1-{3-[3,4-di-O-acetyl-β-D-glucopyranosyl-(1->3)-2-O-acetyl-α-L-rhamnopyranosyloxy]octadecanoyl}-sn-glycerol

: 58479-61-1
tert-butylchlorodiphenylsilane

: 161469-43-8
(S)-3-((tert-butyldiphenylsilyl)oxy)propane-1,2-diol

Guidance literature:: 2-acetyl-1-{3-[3,4-di-O-acetyl-β-D-glucopyranosyl-(1->3)-2-O-acetyl-α-L-rhamnopyranosyloxy]octadecanoyl}-sn-glycerol; tert-butylchlorodiphenylsilane; With pyridine; at 20 ℃; for 12h;

With diisobutylaluminium hydride;
DOI:10.1016/j.phytol.2010.11.001