3-Pentenoic acid ethyl ester

Base Information

• Chemical Name: 3-Pentenoic acid ethyl ester
• CAS No.: 1617-05-6
• Molecular Formula: C7H12O2
• Molecular Weight: 128.171
• Mol file: 1617-05-6.mol

Synonyms:pent-3-enoic acid ethyl ester;Pent-3-ensaeure-aethylester;Pent-3-ensaeure-ethylester;Ethylpropenylacetat;ethyl-3-pentenoate;

Chemical Property of 3-Pentenoic acid ethyl ester

Chemical Property:

• Vapor Pressure: 4.75mmHg at 25°C
• PSA: 26.30000
• LogP: 1.51570

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 3-Pentenoic acid ethyl ester

There total 5 articles about 3-Pentenoic acid ethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 30.0%

ethanol (64-17-5) + 5-methyl-dihydro-furan-2-one (108-29-2) → ethyl 2-pentenoate (2445-93-4) + ethyl pent-3-enoate (1617-05-6)

Guidance literature:

With nitrogen; at 240 ℃; for 3h; under 22502.3 Torr; Autoclave;

DOI:10.1021/cs501409s

Reference yield:

ethanol (64-17-5) + 5-methyl-dihydro-furan-2-one (108-29-2) → ethyl n-valerate (539-82-2) + ethyl pent-3-enoate (1617-05-6) + 4-ethoxy pentanoic acid ethyl ester

Guidance literature:

With zirconia-modified silica-supported copper; hydrogen; at 250 ℃; for 20h; under 7500.75 Torr; Reagent/catalyst; Autoclave;

DOI:10.1039/c2ra23043g

Reference yield:

ethanol (64-17-5) + 5-methyl-dihydro-furan-2-one (108-29-2) → ethyl n-valerate (539-82-2) + ethyl pent-3-enoate (1617-05-6) + ethyl 4-pentenoate (1968-40-7) + Ethyl γ-hydroxyvalerate (6149-46-8) + 4-ethoxy pentanoic acid ethyl ester

Guidance literature:

With hydrogen; at 200 ℃; for 10h; under 22502.3 Torr; Catalytic behavior; Autoclave;

DOI:10.1039/c4ra05250a

upstream raw materials:

ethanol

5-methyl-dihydro-furan-2-one

Refernces

• 1、 Zhang, Damin,Ye, Feiyang,Guan, Yejun,Wang, Yimeng,Hensen, Emiel J. M.. "Hydrogenation of γ-valerolactone in ethanol over Pd nanoparticles supported on sulfonic acid functionalized MIL-101". . p. 39558 - 39564. Retrieved 2014.