[ruthenium(0)(η4-1,3-cyclohexadiene)(η4-1,5-COD)(benzonitrile)]

Base Information

• Chemical Name: [ruthenium(0)(η4-1,3-cyclohexadiene)(η4-1,5-COD)(benzonitrile)]
• CAS No.: 1373229-36-7
• Molecular Formula: C₂₁H₂₅NRu
• Molecular Weight: 392.506
• Mol file: 1373229-36-7.mol

Synonyms:

Chemical Property of [ruthenium(0)(η4-1,3-cyclohexadiene)(η4-1,5-COD)(benzonitrile)]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [ruthenium(0)(η4-1,3-cyclohexadiene)(η4-1,5-COD)(benzonitrile)]

There total 1 articles about [ruthenium(0)(η4-1,3-cyclohexadiene)(η4-1,5-COD)(benzonitrile)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(η6-naphthalene)(η4-1,5-cyclooctadiene)ruthenium(0) (88945-10-2) + cyclohexa-1,3-diene (1165952-91-9) + benzonitrile (100-47-0) → [ruthenium(0)(η4-1,3-cyclohexadiene)(η4-1,5-COD)(benzonitrile)] (1373229-36-7)

Guidance literature:

In acetonitrile; benzene; byproducts: naphthalene; under N2, Schlenk and vacuum techniques; suspn. of Ru complex (NCCH3) treated with satd. soln. of C6H8 (benzene) at room temp. for 1 h, then treated with NCPh; evapd. to dryness under vac., extracted with hexane, filtered, concd. (vac.), crystd. at cooling for 2 d (dry ice);

DOI:10.1016/j.jorganchem.2012.02.018

Reference yield: 10.0%

[ruthenium(0)(η4-1,3-cyclohexadiene)(η4-1,5-COD)(benzonitrile)] (1373229-36-7) + cyclohexa-1,3-diene (1165952-91-9) → ruthenium(0)(η4-1,3-cyclohexadiene)2(benzonitrile) (142084-93-3)

Guidance literature:

In acetonitrile; benzene; byproducts: 1,5-COD; Schlenk technique, under N2; soln. of Ru complex left in contact wiyh C6H8 for several h;

DOI:10.1016/j.jorganchem.2012.02.018

upstream raw materials:

(η6-naphthalene)(η4-1,5-cyclooctadiene)ruthenium(0)

cyclohexa-1,3-diene

benzonitrile

Downstream raw materials:

ruthenium(0)(η4-1,3-cyclohexadiene)2(benzonitrile)