Dibromomethyl radical

Base Information

• Chemical Name: Dibromomethyl radical
• CAS No.: 14362-13-1
• Molecular Formula: CHBr₂
• Molecular Weight: 172.827
• DSSTox Substance ID: DTXSID10162481
• Nikkaji Number: J982.824I
• Mol file: 14362-13-1.mol

Synonyms:Dibromomethyl radical;Methyl, dibromo-;14362-13-1;CHBr2;DTXSID10162481

Chemical Property of Dibromomethyl radical

Chemical Property:

• XLogP3: 1.8
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 172.84245
• Heavy Atom Count: 3
• Complexity: 2.8

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: [CH](Br)Br

Technology Process of Dibromomethyl radical

There total 5 articles about Dibromomethyl radical which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

Bromoform (75-25-2) → dibromomethyl (14362-13-1)

Guidance literature:

In solid matrix; Irradiation (UV/VIS); vacuum UV-photolysis of CHBr3 in an Ar-matrix at 14K;; determination by IR;;

DOI:10.1063/1.1673285

Reference yield:

1,1-dibromomethane (74-95-3) → dibromomethyl (14362-13-1)

Guidance literature:

With chlorine; at -42.1 - 22.9 ℃; under 700 Torr; Rate constant; Kinetics; Irradiation; velocity constants of the reaction of CH₂Br₂ with Cl atom;

DOI:10.1002/(SICI)1097-4601(1996)28:6<433::AID-KIN5>3.0.CO;2-W

Reference yield:

1,1-dibromomethane (74-95-3) → dibromomethyl (14362-13-1)

Guidance literature:

With chlorine; under 21 Torr; Thermodynamic data; Irradiation; ΔH(excit.);

DOI:10.1021/j100317a023

upstream raw materials:

1,1-dibromomethane

Bromoform