2-Butenoic acid, 2-methyl-, ethyl ester, (2Z)-

Base Information

Chemical Name:2-Butenoic acid, 2-methyl-, ethyl ester, (2Z)-
CAS No.:16509-44-7
Molecular Formula:C7H12O2
Molecular Weight:128.171
Hs Code.:
Mol file:16509-44-7.mol

Synonyms:2-methyl-cis-crotonic acid ethyl ester;2-Methyl-cis-crotonsaeure-aethylester;ethyl (Z)-2-methyl-2-butenoate;ethyl (E)-2-methylbut-2-enoate;cis-2-Methylcrotonsaeure-ethylester;ethyl angelate;

Suppliers and Price of 2-Butenoic acid, 2-methyl-, ethyl ester, (2Z)-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
AngelicAcidEthylEster
1g
$ 1230.00

TRC
AngelicAcidEthylEster
100mg
$ 155.00

Total 2 raw suppliers

Chemical Property of 2-Butenoic acid, 2-methyl-, ethyl ester, (2Z)-

Chemical Property:

Boiling Point:140-144 °C
PSA：26.30000
Density:0.916 g/cm3
LogP:1.51570

Purity/Quality:

98%,99%, ^*data from raw suppliers

AngelicAcidEthylEster ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Uses Angelic Acid Ethyl Ester is a reactant used in the synthesis of bicyclo[1.1.0]butane-1 and 2-carboxylate esters.

Technology Process of 2-Butenoic acid, 2-methyl-, ethyl ester, (2Z)-

There total 15 articles about 2-Butenoic acid, 2-methyl-, ethyl ester, (2Z)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 40.0%

: 5837-78-5,55514-48-2
Ethyl tiglate

: 16509-44-7,55514-48-2
ethyl (Z)-2-methyl-2-butenoate

: 1647-12-7
ethyl 2-methyl-but-3-enoate

Guidance literature:: aluminium trichloride; In dichloromethane; for 3.5h; Irradiation;
DOI:10.1021/ja00271a034

Reference yield:

: 81171-50-8
(2-Chloro-1-ethoxy-2,3-dimethyl-cyclopropoxy)-trimethyl-silane

: 16509-44-7,55514-48-2
ethyl (Z)-2-methyl-2-butenoate

: 5837-78-5,55514-48-2
Ethyl tiglate

Guidance literature:: With triethylamine; In methanol; for 6h; Yield given. Yields of byproduct given; Heating;
DOI:10.1055/s-1982-29699

Reference yield:

: 3070-65-3
ethyl 2-methylenebutyrate

: 7452-79-1,53956-13-1
ethyl 2-methylbutyrate

: 16509-44-7,55514-48-2
ethyl (Z)-2-methyl-2-butenoate

: 5837-78-5,55514-48-2
Ethyl tiglate

Guidance literature:: With hydrogen; palladium on activated charcoal; In ethanol; at 20 ℃; for 0.0833333h; Product distribution; the formed intermediates are separated with gas chromatography and detected with 1H-NMR-spectroscopy after several times;