Oxido[10]annulene

Base Information

• Chemical Name: Oxido[10]annulene
• CAS No.: 4759-11-9
• Molecular Formula: C10H8 O
• Molecular Weight: 144.173
• Mol file: 4759-11-9.mol

Synonyms:1,6-Epoxy[10]annulene;1,6-Oxido[10]annulene;

Chemical Property of Oxido[10]annulene

Chemical Property:

• Vapor Pressure: 6.39E-06mmHg at 25°C
• Refractive Index: 1.616
• Boiling Point: 389.4°C at 760 mmHg
• Flash Point: 187.5°C
• PSA: 9.23000
• Density: 1.11g/cm³
• LogP: 2.91670

Purity/Quality:

99% ^*data from raw suppliers

11-OXABICYCLO[4.4.1]UNDECA-1,3,5,7,9-PENTAENE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Oxido[10]annulene

There total 1 articles about Oxido[10]annulene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

→ 11-oxido-1,6-methano<10>annulene (4759-11-9)

Guidance literature:

Beim Behandeln von 2.3.6.7-Tetrabrom-4a.8a-epoxy-decalin (Isomerengemisch) mit Kalium-tert.-butylat in Aether bei -10grad;

Reference yield:

11-oxido-1,6-methano<10>annulene (4759-11-9) → α-naphthol (90-15-3) + 1-naphthol-2-sulfonic acid (567-18-0) + 1-hydroxy-4-naphthalenesulfonate (84-87-7) + 1-Naphthol sulfate (3197-94-2)

Guidance literature:

With sulfur trioxide; In 1,4-dioxane; dichloromethane; at 0 ℃; for 3.88889h; Product distribution; Mechanism; various temperatures, various reaction times; different molar eqiv of SO3; also without methylene chloride; other bridged <10>annulenes;

DOI:10.1021/jo00363a030

Reference yield:

11-oxido-1,6-methano<10>annulene (4759-11-9) + 4-Phenyl-1,2,4-triazolidine-3,5-dione (4233-33-4) → 5a,12a-epoxy-2,9-diphenyl-(5ac,12ac)-5a,6,12a,13-tetrahydro-5H,12H-5r,13c;6c,12c-dietheno-[1,2,4]triazolo[1,2-a][1,2,4]triazolo[1',2':1,2]pyridazino[4,5-d]pyridazine-1,3,8,10-tetraone (64806-90-2)

Guidance literature:

DOI:10.1016/0040-4020(77)80409-2

Downstream raw materials:

5a,12a-epoxy-2,9-diphenyl-(5ac,12ac)-5a,6,12a,13-tetrahydro-5H,12H-5r,13c;6c,12c-dietheno-[1,2,4]triazolo[1,2-a][1,2,4]triazolo[1',2':1,2]pyridazino[4,5-d]pyridazine-1,3,8,10-tetraone

α-naphthol

1-naphthol-2-sulfonic acid

1-hydroxy-4-naphthalenesulfonate