Iron,tetracarbonyl(trimethylphosphine)-, (TB-5-12)-

Base Information

• Chemical Name: Iron,tetracarbonyl(trimethylphosphine)-, (TB-5-12)-
• CAS No.: 18475-02-0
• Molecular Formula: C₇H₉FeO₄P
• Molecular Weight: 243.967
• Mol file: 18475-02-0.mol

Synonyms:Iron,tetracarbonyl(trimethylphosphine)- (8CI); Tetracarbonyl(trimethylphosphine)iron

Chemical Property of Iron,tetracarbonyl(trimethylphosphine)-, (TB-5-12)-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Iron,tetracarbonyl(trimethylphosphine)-, (TB-5-12)-

There total 3 articles about Iron,tetracarbonyl(trimethylphosphine)-, (TB-5-12)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 35.0%

{Fe(CO)3(P(CH3)3)(H)(Si(C6H5)3)} + triphenylphosphine (603-35-0) → iron(carbonyl)3(trimethylphosphine)2 (30230-16-1) + Fe(CO)4(PMe3) (18475-02-0) + {Fe(CO)3(P(CH3)3)(P(C6H5)3)} (130102-27-1)

Guidance literature:

In benzene; byproducts: HSiPh3; addn. of a five-fold excess of PPh3 to soln. of Fe-compound in benzene at 60°C;; removal of solvent under vac.; washed with n-hexane; recrystn. from ethyl ether; elem. anal.;

DOI:10.1016/0022-328X(90)85062-4

Reference yield:

duryldibromoborane (1359988-81-0) + K[Fe(CO)3(PMe3)(SiEt3)] → iron(carbonyl)3(trimethylphosphine)2 (30230-16-1) + Fe(CO)4(PMe3) (18475-02-0) + C12H18BBr

Guidance literature:

duryldibromoborane; K[Fe(CO)3(PMe₃)(SiEt₃)]; In hexane; at 20 ℃; for 6h;

at 60 ℃; under 0.000750075 Torr;

DOI:10.1039/c5cc06425b

Reference yield:

{Fe(CO)3(P(CH3)3)(H)(Si(C6H5)3)} + tricyclohexylphosphine (2622-14-2) → iron(carbonyl)3(trimethylphosphine)2 (30230-16-1) + Fe(CO)4(PMe3) (18475-02-0) + [Fe(CO)4(PCy3)] (18474-81-2) + {Fe(CO)3(P(CH3)3)(P(C6H11)3)} (188618-29-3)

Guidance literature:

In benzene; react. carried out in benzene at 60°C with a 3-5-fold excess of P(C6H11)3; compleated in 3-4 h; (31)P NMR; IR;

DOI:10.1016/0022-328X(90)85062-4

upstream raw materials:

tricyclohexylphosphine

triphenylphosphine

duryldibromoborane

Downstream raw materials:

{N(CH₂CH₃)4}⁽¹⁺⁾*{((C₆H₅)3Sn)Fe(CO)3(P(CH₃)3)}^(1-)={N(CH₂CH₃)4}{((C₆H₅)3Sn)Fe(CO)3(P(CH₃)3)}

tricarbonyl bis(triphenylphosphine) iron

{Fe(CO)3(P(CH₃)3)(P(C₆H₅)3)}

(OC-6-23)-tricarbonylhydrido(trimethylphosphine)(triphenylsilyl)iron