5-(4-Carboxymethylphenyl)dipyrromethane (under argon)

Base Information

• Chemical Name: 5-(4-Carboxymethylphenyl)dipyrromethane (under argon)
• CAS No.: 167482-99-7
• Molecular Formula: C17H16N2O2
• Molecular Weight: 280.326
• Mol file: 167482-99-7.mol

Synonyms:

Chemical Property of 5-(4-Carboxymethylphenyl)dipyrromethane (under argon)

Chemical Property:

• Melting Point: 160-162 °C
• Boiling Point: 486.6±40.0 °C(Predicted)
• PKA: 16.74±0.50(Predicted)
• PSA: 57.88000
• Density: 1.233±0.06 g/cm3(Predicted)
• LogP: 3.30960

Purity/Quality:

97% ^*data from raw suppliers

5-(4-CARBOXYMETHYLPHENYL)DIPYRROMETHANE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 5-(4-Carboxymethylphenyl)dipyrromethane (under argon)

There total 8 articles about 5-(4-Carboxymethylphenyl)dipyrromethane (under argon) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

pyrrole (109-97-7,30604-81-0) + methyl 4-formylbenzoate (1571-08-0) → 5-(4-carbomethoxyphenyl)dipyrromethane (167482-99-7)

Guidance literature:

With trifluoroacetic acid; at 20 ℃; for 0.166667h;

DOI:10.1515/znb-2005-0710

Reference yield: 75.0%

methyl 4-formylbenzoate (1571-08-0) → 5-(4-carbomethoxyphenyl)dipyrromethane (167482-99-7)

Guidance literature:

Conversion of starting material;

Reference yield: 68.0%

4,4-difluoro-8-(4’-methoxycarbonylphenyl)-4-bora-3a,4a-diaza-s-indacene (1493817-13-2) → 5-(4-carbomethoxyphenyl)dipyrromethane (167482-99-7)

Guidance literature:

With sodium methylate; at 215 ℃; for 0.166667h; Inert atmosphere; Microwave irradiation;

DOI:10.1139/cjc-2013-0341

upstream raw materials:

pyrrole

methyl 4-formylbenzoate

4,4-difluoro-8-(4’-methoxycarbonylphenyl)-4-bora-3a,4a-diaza-s-indacene

5-(4-(methoxycarbonyl)phenyl)-4,6-dipyrrin

Downstream raw materials:

5,10,15,20-tetrakis(p-tert-butylphenyl)porphyrin

4-[15-(4-nitro-phenyl)-10,20-di-(4-fluoro)phenylporphyrin-5-yl]methyl benzoate

4-[15-(4-nitro-phenyl)-10,20-di-(4-trifluoromethyl)phenylporphyrin-5-yl]methyl benzoate

4,4-difluoro-8-(4’-methoxycarbonylphenyl)-4-bora-3a,4a-diaza-s-indacene

Refernces

• 1、 Aggarwal, Aviral,Elliott, Rory,Ryan, Aoife A.,Schmitt, Wolfgang,Senge, Mathias O.,Steuber, Friedrich W.,Zhu, Nianyong. "2D porphyrinic metal-organic frameworks featuring rod-shaped secondary building units". . . Retrieved 2021.
• 2、 McLean, Tracey M.,Cleland, Deidre,Gordon, Keith C.,Telfer, Shane G.,Waterland, Mark R.. "Raman spectroscopy of dipyrrins: Nonresonant, resonant and surface-enhanced cross-sections and enhancement factors". . p. 2154 - 2164. Retrieved 2011.
• 3、 Saha, Sourav,Johansson, Erik,Flood, Amar H.,Tseng, Hsian-Rong,Zink, Jeffrey I.,Stoddart, J. Fraser. "A photoactive molecular triad as a nanoscale power supply for a supramolecular machine". . p. 6846 - 6858. Retrieved 2005.
• 4、 Harney, Joseph P.,Dransfield, Timothy,Rochford, Jonathan. "Convergent synthesis of meso-ferrocenyl porphyrins for TiO2 sensitization". . p. 4700 - 4703. Retrieved 2012.
• 5、 -. "QUINONE-METHIDE PRECURSORS WITH BODIPY CHROMOPHORE, METHOD OF PREPARATION, BIOLOGICAL ACTIVITY AND APPLICATION IN FLUORESCENT LABELLING". Page/Page column 22. . Retrieved 2017/12/15.