1α,4α-Dichlorocyclohexane

Base Information

• Chemical Name: 1α,4α-Dichlorocyclohexane
• CAS No.: 16749-11-4
• Molecular Formula: C6H10Cl2
• Molecular Weight: 153.051
• Mol file: 16749-11-4.mol

Synonyms:Cyclohexane, 1,4-dichloro-, cis-;cis-1,4-Dichlorocyclohexan;cis-1.4-Dichlor-cyclohexan;cis-1,4-Dichlor-cyclohexan;cis-1,4-dichloro-cyclohexane;1,4-cis-Dichlor-cyclohexan;

Chemical Property of 1α,4α-Dichlorocyclohexane

Chemical Property:

• Melting Point: 18°C
• Refractive Index: 1.4942
• Boiling Point: 181.5°C (rough estimate)
• PSA: 0.00000
• Density: 1.1900
• LogP: 2.77520

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1α,4α-Dichlorocyclohexane

There total 10 articles about 1α,4α-Dichlorocyclohexane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 4.9%

cyclohexyl chloride (542-18-7) → 1,1-dichlrocyclohexane (2108-92-1) + 1,3-cis-dichlorocyclohexane (24955-63-3) + trans-1,4-dichlorocyclohexane (16890-91-8) + 1,4-cis-dichlorocyclohexane (16749-11-4) + trans-1,2-dichlorocyclohexane (822-86-6) + 1,3-trans-dichlorocyclohexane (24955-62-2,24955-63-3,55887-78-0)

Guidance literature:

With chlorine; In tetrachloromethane; Product distribution; Irradiation; investigation of the photochlorination;

DOI:10.1021/ja00219a028

Reference yield:

cyclohexane (110-82-7,25012-93-5) → cyclohexyl chloride (542-18-7) + 1,3-cis-dichlorocyclohexane (24955-63-3) + trans-1,4-dichlorocyclohexane (16890-91-8) + 1,4-cis-dichlorocyclohexane (16749-11-4) + trans-1,2-dichlorocyclohexane (822-86-6) + 1,3-trans-dichlorocyclohexane (24955-62-2,24955-63-3,55887-78-0)

Guidance literature:

With chlorine; In tetrachloromethane; at 20 - 230 ℃; Product distribution; Kinetics; investigation of the free-radicals chlorination of alkanes in various solvent system;

DOI:10.1021/ja00219a028

Reference yield:

trans-4-hydroxycyclohexyl chloride (29538-77-0) → 4-chlorocyclohexene (930-65-4) + 1,4-cis-dichlorocyclohexane (16749-11-4)

Guidance literature:

With pyridine; thionyl chloride; chloroform;

DOI:10.1021/ja01133a516

upstream raw materials:

trans-4-hydroxycyclohexyl chloride

cyclohexane

cyclohexyl chloride

7-oxabicyclo(2.2.1)heptane

Refernces