930-65-4

Basic information

• Product Name: 4-CHLOROCYCLOHEXENE
• Synonyms: 4-CHLOROCYCLOHEXENE;Chlorocyclohexene: (4-Chlorocyclohexene);4-Chloro-1-cyclohexene
• CAS NO: 930-65-4
• Molecular Formula: C₆H₉Cl
• Molecular Weight: 116.59
• Mol File: 930-65-4.mol
• Article Data: 3

Chemical Properties

• Boiling Point: 150 °C at 760 mmHg
• Flash Point: 28.8 °C
• Appearance: /
• Density: 1.02 g/cm³
• Vapor Pressure: 4.98mmHg at 25°C
• Refractive Index: 1.48
• Storage Temp.: Refrigerator, Under inert atmosphere
• Solubility: Chloroform (Slightly), Dichloromethane (Slightly), Ethanol (Slightly)
• CAS DataBase Reference: 4-CHLOROCYCLOHEXENE(CAS DataBase Reference)
• NIST Chemistry Reference: 4-CHLOROCYCLOHEXENE(930-65-4)
• EPA Substance Registry System: 4-CHLOROCYCLOHEXENE(930-65-4)

Safety Data

• Hazardous Substances Data: 930-65-4(Hazardous Substances Data)

Usage

Uses

4-Chlorocyclohexene is a 4-substituted cyclohexene that has been used to create bicyclo[3.1.0]hexane rings via zirconium y-elimination.

Synthesis Reference(s)

Journal of the American Chemical Society, 107, p. 7978, 1985 DOI: 10.1021/ja00312a030

InChI:InChI=1/C6H9Cl/c7-6-4-2-1-3-5-6/h1-2,6H,3-5H2

Upstream product

• 30485-71-3 4-chlorocyclohexanol 
• 556-48-9 1,4-Cyclohexanediol 
• 932-67-2 cyclohex-3-enecarbonyl chloride 
• 100-50-5 3-Cyclohexene-1-carboxaldehyde 
• 110-83-8 cyclohexene 
• 4771-80-6 1,2,5,6-tetrahydrobenzoic acid 
• 186-04-9 bicyclo[2.2.0]hexane 
• 29538-77-0 trans-4-hydroxycyclohexyl chloride 
• 120-18-3 naphthalene-2-sulfonate 

Relevant articles and documents

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MECHANISMS OF EPOXIDATIONS AND CHLORINATIONS OF HYDROCARBONS BY INORGANIC HYPOCHLORITE IN THE PRESENCE OF A PHASE-TRANSFER CATALYST.

Inorganic hypochlorite in the presence of a quarternary ammonium salt (phase-transfer catalyst) not only epoxidizes several arenes to arene oxides in high yields but also converts toluene to alpha -chlorotoluene, anisole to ring chlorinated anisoles, and alkenes to a complex mixture of chlorinated and oxidized products, including the epoxide. More detailed studies with this system indicate the following: (1) the high-yield conversion of toluenes to benzyl chlorides proceeds with a deuterium isotope effect of 3. 6 and a rho ** plus value of minus 1. 7: (2) p-chloroanisole is the major product from anisole and is formed in a 22-fold greater quantity than o-chloroanisole; (3) the epoxidation of cis- and trans-alkenes is stereoselective but not completely stereospecific; (4) the chlorination of saturated hydrocarbons occurs with a selectivity that is experimentally identical with that of chlorine monoxide.