4,4,5,5-Tetramethyl-2-(4-phenylbutyl)-1,3,2-dioxaborolane

Base Information

Chemical Name:4,4,5,5-Tetramethyl-2-(4-phenylbutyl)-1,3,2-dioxaborolane
CAS No.:167693-07-4
Molecular Formula:C16H25BO2
Molecular Weight:260.184
Hs Code.:
DSSTox Substance ID:DTXSID40570616
Nikkaji Number:J3.316.541B
Wikidata:Q82458123

Synonyms:4,4,5,5-tetramethyl-2-(4-phenylbutyl)-1,3,2-dioxaborolane;167693-07-4;SCHEMBL3769043;DTXSID40570616

Suppliers and Price of 4,4,5,5-Tetramethyl-2-(4-phenylbutyl)-1,3,2-dioxaborolane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 4,4,5,5-Tetramethyl-2-(4-phenylbutyl)-1,3,2-dioxaborolane

Chemical Property:

PSA：18.46000
LogP:4.10150
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:5
Exact Mass:260.1947602
Heavy Atom Count:19
Complexity:267

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:B1(OC(C(O1)(C)C)(C)C)CCCCC2=CC=CC=C2

Technology Process of 4,4,5,5-Tetramethyl-2-(4-phenylbutyl)-1,3,2-dioxaborolane

There total 41 articles about 4,4,5,5-Tetramethyl-2-(4-phenylbutyl)-1,3,2-dioxaborolane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 74-97-5
chlorobromomethane

: 329685-40-7
4,4,5,5-tetramethyl-2-(3-phenylpropyl)-[1,3,2]dioxaborolane

: 167693-07-4
4-phenyl-1-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)butane

Guidance literature:: With n-butyllithium; In tetrahydrofuran; hexane; at -40 - 40 ℃; Temperature; Schlenk technique; Flow reactor;
DOI:10.1021/acs.orglett.1c01222

Reference yield: 98.0%

: 768-56-9
4-Phenylbut-1-ene

: 25015-63-8
4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane

: 167693-07-4
4-phenyl-1-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)butane

Guidance literature:: Wilkinson's catalyst; In dichloromethane; 25°C, 10 min;
DOI:10.1021/ja952653z

Reference yield: 84.0%

: 13633-25-5
1-Bromo-4-phenylbutane

: 73183-34-3
bis(pinacol)diborane

: 167693-07-4
4-phenyl-1-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)butane

Guidance literature:: bis(pinacol)diborane; With 1-hexene; tetrakis(acetonitrile)copper(I)tetrafluoroborate; potassium tert-butylate; 1,3-bis(mesityl)imidazolium chloride; zinc dibromide; In 1,4-dioxane; N,N-dimethyl-formamide; at 20 ℃; for 0.0166667h; Glovebox; Inert atmosphere;

1-Bromo-4-phenylbutane; In 1,4-dioxane; N,N-dimethyl-formamide; at 50 ℃;
DOI:10.1021/jacs.1c02050