Phosphine, [2-(chloromethyl)phenyl]diphenyl-

Base Information

Chemical Name:Phosphine, [2-(chloromethyl)phenyl]diphenyl-
CAS No.:167706-40-3
Molecular Formula:C19H16ClP
Molecular Weight:310.763
Hs Code.:
DSSTox Substance ID:DTXSID50479383
Mol file:167706-40-3.mol

Synonyms:Phosphine, [2-(chloromethyl)phenyl]diphenyl-;167706-40-3;DTXSID50479383;(2-(Chloromethyl)phenyl)diphenylphosphane

Suppliers and Price of Phosphine, [2-(chloromethyl)phenyl]diphenyl-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Phosphine, [2-(chloromethyl)phenyl]diphenyl-

Chemical Property:

PSA：13.59000
LogP:4.18360
XLogP3:5
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:4
Exact Mass:310.0678152
Heavy Atom Count:21
Complexity:276

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3CCl

Technology Process of Phosphine, [2-(chloromethyl)phenyl]diphenyl-

There total 4 articles about Phosphine, [2-(chloromethyl)phenyl]diphenyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 62.0%

: 53881-33-7
[2-(N,N-dimethylaminomethyl)phenyl]diphenylphosphane

: 167706-40-3
(2-(chloromethyl)phenyl)diphenyl phosphine

Guidance literature:: With chloroformic acid ethyl ester; In toluene; Reflux; Inert atmosphere; Schlenk technique; Glovebox;
DOI:10.1039/d1ob00362c

Reference yield:

: 103-83-3
N,N'-dimethylbenzylamine

: 167706-40-3
(2-(chloromethyl)phenyl)diphenyl phosphine

Guidance literature:: Multi-step reaction with 2 steps

1.1: n-BuLi / diethyl ether / 20 °C

1.2: diethyl ether / -78 - 20 °C

2.1: ethyl chloroformate / benzene / Heating

With n-butyllithium; chloroformic acid ethyl ester; In diethyl ether; benzene;
DOI:10.1016/j.tet.2004.10.049

Reference yield:

: 1079-66-9,74391-44-9
chloro-diphenylphosphine

: 167706-40-3
(2-(chloromethyl)phenyl)diphenyl phosphine

Guidance literature:: Multi-step reaction with 2 steps

1: n-butyllithium

2: chloroformic acid ethyl ester

With n-butyllithium; chloroformic acid ethyl ester;
DOI:10.1002/zaac.201800151