Rh2(μ-OPh)2(C2H4)4

Base Information

Chemical Name:Rh2(μ-OPh)2(C2H4)4
CAS No.:307548-63-6
Molecular Formula:C₂₀H₂₆O₂Rh₂
Molecular Weight:504.236
Hs Code.:

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Chemical Property of Rh2(μ-OPh)2(C2H4)4

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Technology Process of Rh2(μ-OPh)2(C2H4)4

There total 2 articles about Rh2(μ-OPh)2(C2H4)4 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: chlorobis(ethylene)rhodium(I) dimer

: 139-02-6
sodium phenoxide

: Rh2(η(5)-OPh)(C2H4)2

: 307548-63-6
Rh2(μ-OPh)2(C2H4)4

Guidance literature:: In tetrahydrofuran; benzene; byproducts: NaCl; under N2, THF soln. of NaOPh was added dropwise to colt (283 K) filtered C6H6 soln. of Rh-complex, mixt. was stirred at 283 K for 24 h; summarized yield of Rh-complexes was 73 %; NaCl was filtered off, soln. was concd. in vac., pentane was layered, soln. was cooled to 253 K, 24 h, solid was filtered, washed with pentane,dried in vac., mixt. was repeatedly crystd. from benzene-pentane, elem.anal.;
DOI:10.1016/S0022-328X(00)00217-5

Reference yield:

: chlorobis(ethylene)rhodium(I) dimer

: 100-67-4
potassium phenolate

: 2923-28-6
silver trifluoromethanesulfonate

: Rh2(η(5)-OPh)(C2H4)2

: 307548-63-6
Rh2(μ-OPh)2(C2H4)4

Guidance literature:: In tetrahydrofuran; byproducts: AgCl; under N2, THF soln. of Ag-triflate was added dropwise to colt (263 K) soln. of Rh-complex in nTHF, mixt. was stirred for 30 min, AgCl was filtered off, KOPh was added in THF, stirred at 273 K for 3 h; soln. was concd. in vac., filtered, pentane was added, soln. was cooledto 253 K, 24 h, solid was filtere;
DOI:10.1016/S0022-328X(00)00217-5