ruthenium(6+) azanide - trifluoromethanesulfonic acid (1:6:1)

Base Information

• Chemical Name: ruthenium(6+) azanide - trifluoromethanesulfonic acid (1:6:1)
• CAS No.: 53195-17-8
• Molecular Formula: CH13F3N6O3RuS
• Molecular Weight: 347.2825
• Mol file: 53195-17-8.mol

Synonyms:

Chemical Property of ruthenium(6+) azanide - trifluoromethanesulfonic acid (1:6:1)

Chemical Property:

• Vapor Pressure: 1.14mmHg at 25°C
• Boiling Point: 162°Cat760mmHg
• Flash Point: °C
• Density: g/cm³

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of ruthenium(6+) azanide - trifluoromethanesulfonic acid (1:6:1)

There total 3 articles about ruthenium(6+) azanide - trifluoromethanesulfonic acid (1:6:1) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

hexaammineruthenium(II) chloride (19052-44-9,15305-72-3) + trifluorormethanesulfonic acid (1493-13-6) → Ru(NH3)6(3+)*3OSO2CF3(1-)=(Ru(NH3)6)(OSO2CF3)3 (53195-17-8)

Guidance literature:

With dihydrogen peroxide; In further solvent(s); gentle warming of Ru-complex (in water contg. little CF3SO3H) with 30% H2O2, stirring in ice bath (crystn.), collection, washing (EtOH, Me2CO, Et2O), dissoln. in CF3SO3H, heating to 50-60°C for 30 min (bubbling N2); cooling, pptn. on Et2O addn., collection (filtration), washing (Et2O), recrystn. (aq. CF3SO3H, 5°C overnight), collection (filtration), washing (Et2O), drying (vac.); elem. anal.;

DOI:10.1016/0020-1693(95)04986-X

Reference yield:

hexammine ruthenium(III) chloride (14282-91-8) + silver trifluoromethanesulfonate (2923-28-6) → Ru(NH3)6(3+)*3OSO2CF3(1-)=(Ru(NH3)6)(OSO2CF3)3 (53195-17-8)

Guidance literature:

In water;

DOI:10.1021/ic400062b

Reference yield:

hexammine ruthenium(III) chloride (14282-91-8) + trifluorormethanesulfonic acid (1493-13-6) → Ru(NH3)6(3+)*3OSO2CF3(1-)=(Ru(NH3)6)(OSO2CF3)3 (53195-17-8)

Guidance literature:

In water; under exclusion of oxygen; Ru complex dissolved in water; pptd. several times with CF3SO3H; elem. anal.;

DOI:10.1039/b210256k

upstream raw materials:

hexammine ruthenium(III) chloride

trifluorormethanesulfonic acid

hexaammineruthenium(II) chloride

silver trifluoromethanesulfonate