p-Isopropenylphenyl glycidyl ether

Base Information

Chemical Name:p-Isopropenylphenyl glycidyl ether
CAS No.:17071-45-3
Molecular Formula:C12H14O2
Molecular Weight:190.23800
Hs Code.:2910900090
DSSTox Substance ID:DTXSID60569426
Nikkaji Number:J59.935B
Mol file:17071-45-3.mol

Synonyms:p-isopropenylphenyl glycidyl ether;17071-45-3;2-[(4-prop-1-en-2-ylphenoxy)methyl]oxirane;SCHEMBL573700;DTXSID60569426;ZDTYPPLWITYVRR-UHFFFAOYSA-N;2-{[4-(Prop-1-en-2-yl)phenoxy]methyl}oxirane

Suppliers and Price of p-Isopropenylphenyl glycidyl ether

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
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price

Total 1 raw suppliers

Chemical Property of p-Isopropenylphenyl glycidyl ether

Chemical Property:

PSA：21.76000
LogP:2.49730
XLogP3:3
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:4
Exact Mass:190.099379685
Heavy Atom Count:14
Complexity:204

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(=C)C1=CC=C(C=C1)OCC2CO2

Technology Process of p-Isopropenylphenyl glycidyl ether

There total 5 articles about p-Isopropenylphenyl glycidyl ether which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

: 4286-23-1,64054-77-9
4-isopropenylphenol

: 106-89-8,24969-06-0,13403-37-7
epichlorohydrin

: 17071-45-3
(4-isopropenyl-phenoxymethyl)-oxirane

Guidance literature:: 4-isopropenylphenol; epichlorohydrin; With triethylamine; at 90 ℃; for 1h; Inert atmosphere;

With sodium hydroxide; at 40 ℃; for 2h; Inert atmosphere;
DOI:10.1002/pola.27914

Reference yield:

: 19152-55-7
1-[4-(2-oxiranylmethoxy)phenyl]-1-ethanone

: 1779-49-3
Methyltriphenylphosphonium bromide

: 17071-45-3
(4-isopropenyl-phenoxymethyl)-oxirane

Guidance literature:: Methyltriphenylphosphonium bromide; With potassium tert-butylate; In tetrahydrofuran; at 0 ℃; for 0.75h;

1-[4-(2-oxiranylmethoxy)phenyl]-1-ethanone; In tetrahydrofuran; at 20 ℃; for 18h;
DOI:10.1021/acs.orglett.8b01600

Reference yield:

: 99-93-4
4-Hydroxyacetophenone

: 17071-45-3
(4-isopropenyl-phenoxymethyl)-oxirane

Guidance literature:: Multi-step reaction with 2 steps

1.1: potassium carbonate / acetone / Reflux

2.1: potassium tert-butylate / tetrahydrofuran / 0.75 h / 0 °C

2.2: 18 h / 20 °C

With potassium tert-butylate; potassium carbonate; In tetrahydrofuran; acetone;
DOI:10.1021/acs.orglett.8b01600