Dimethyl tetramethylsuccinate

Base Information

• Chemical Name: Dimethyl tetramethylsuccinate
• CAS No.: 17072-58-1
• Molecular Formula: C10H18O4
• Molecular Weight: 202.251
• UNII: 0G000AAF3I
• DSSTox Substance ID: DTXSID60456180
• Nikkaji Number: J1.768.067F
• Wikidata: Q27236725
• Mol file: 17072-58-1.mol

Synonyms:17072-58-1;dimethyl tetramethylsuccinate;Butanedioic acid, tetramethyl-, dimethyl ester;Dimethyl 2,2,3,3-tetramethylbutanedioate;dimethyl 2,2,3,3-tetramethylsuccinate;0G000AAF3I;Dimethyl(2,2,3,3- tetramethyl)succinate;Succinic acid, tetramethyl-, dimethyl ester;Butanedioic acid, 2,2,3,3-tetramethyl-, 1,4-dimethyl ester;UNII-0G000AAF3I;SCHEMBL1424791;DTXSID60456180;JMAVQGUNDSXRMY-UHFFFAOYSA-N;dimethyl2,2,3,3-tetramethylsuccinate;tetramethyl succinic acid dimethyl ester;2,2,3,3-(TETRAMETHYL)DIMETHYLSUCCINATE;2,2,3,3-Tetramethylbutanedioic acid dimethyl ester;1,4-DIMETHYL 2,2,3,3-TETRAMETHYLBUTANEDIOATE;2,2,3,3-tetramethyl-butanedioic acid dimethyl ester;Q27236725

Chemical Property of Dimethyl tetramethylsuccinate

Chemical Property:

• XLogP3: 1.7
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 5
• Exact Mass: 202.12050905
• Heavy Atom Count: 14
• Complexity: 215

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(C)(C(=O)OC)C(C)(C)C(=O)OC

Technology Process of Dimethyl tetramethylsuccinate

There total 14 articles about Dimethyl tetramethylsuccinate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

1-methoxy-2-methyl-1-trimethylsiloxy-1-propene (31469-15-5) + benzil (134-81-6) → C22H28O4Si (1032129-60-4) + tetramethyl-succinic acid dimethyl ester (17072-58-1) + methyl 2,2-dimethyl-3-oxo-3-phenylpropanoate (64407-08-5)

Guidance literature:

In acetonitrile; for 4h; Irradiation;

DOI:10.1021/jo800473x

Reference yield: 53.0%

1-methoxy-2-methyl-1-trimethylsiloxy-1-propene (31469-15-5) + 1-Phenylpropane-1,2-dione (579-07-7) → C14H18O4 (1032129-67-1) + C17H26O4Si (1032129-66-0) + tetramethyl-succinic acid dimethyl ester (17072-58-1)

Guidance literature:

In acetone; for 2h; Irradiation;

DOI:10.1021/jo800473x

Reference yield: 40.0%

1,1-dimethoxy-2-methylprop-1-ene (5634-54-8) → 3,3-dimethyl-2,2,4-trimethoxy-4-phenyloxetane (49784-74-9) + tetramethyl-succinic acid dimethyl ester (17072-58-1)

Guidance literature:

With benzoic acid methyl ester; In hexane; for 30h; Irradiation;

DOI:10.1021/jo00262a031

upstream raw materials:

dimethyl 2,2'-azobis(isobutyrate)

N-chloro-N-phenylbenzamide

benzene

N-chloroacetanilide

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