1-(2-Methoxyphenyl)cycloheptene

Base Information

Chemical Name:1-(2-Methoxyphenyl)cycloheptene
CAS No.:92862-65-2
Molecular Formula:C14H18 O
Molecular Weight:202.2921
Hs Code.:
NSC Number:127377
DSSTox Substance ID:DTXSID00298985

Synonyms:92862-65-2;1-(2-methoxyphenyl)cycloheptene;NSC127377;DTXSID00298985;NSC-127377

Suppliers and Price of 1-(2-Methoxyphenyl)cycloheptene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 4 raw suppliers

Chemical Property of 1-(2-Methoxyphenyl)cycloheptene

Chemical Property:

Vapor Pressure:0.000847mmHg at 25°C
Boiling Point:314.7°C at 760 mmHg
Flash Point:123.3°C
Density:0.993g/cm³
XLogP3:4.2
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:2
Exact Mass:202.135765193
Heavy Atom Count:15
Complexity:219

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:COC1=CC=CC=C1C2=CCCCCC2

Technology Process of 1-(2-Methoxyphenyl)cycloheptene

There total 4 articles about 1-(2-Methoxyphenyl)cycloheptene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 62.0%

: cyclohept-1-en-1-yl 4-methylbenzenesulfonate

: 16750-63-3
2-methoxyphenylmagnesium bromide

: 92862-65-2
(E)-1-(2-methoxyphenyl)cyclohept-1-en

Guidance literature:: 2-methoxyphenylmagnesium bromide; With tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; 4,4,5,5-tetramethyl<1,3,2>dioxaphospholane-2-oxide; In tetrahydrofuran; at 20 ℃; for 0.0833333h; Inert atmosphere;

cyclohept-1-en-1-yl 4-methylbenzenesulfonate; In tetrahydrofuran; at 60 ℃; for 22h; chemoselective reaction; Inert atmosphere;
DOI:10.1002/chem.201002386

Reference yield:

: 90-05-1
2-methoxy-phenol

: o-(3-Cycloheptenyl)-anisol

: 92862-65-2
(E)-1-(2-methoxyphenyl)cyclohept-1-en

Guidance literature:: Multi-step reaction with 2 steps

1: pyridine / dichloromethane / 5 h / 25 °C / Inert atmosphere

2: bis(1,1,1,5,5,5-hexafluoro-2,4-pentanedionato)palladium(II); 1,3-bis-(diphenylphosphino)propane; lithium carbonate; 1,2-dimethoxybenzene / 72 h / 120 °C / Inert atmosphere

With pyridine; 1,2-dimethoxybenzene; bis(1,1,1,5,5,5-hexafluoro-2,4-pentanedionato)palladium(II); 1,3-bis-(diphenylphosphino)propane; lithium carbonate; In dichloromethane; 2: |Heck Reaction;
DOI:10.1002/chem.201204427

Reference yield:

: 628-92-2,45509-99-7
Cycloheptene

: 59099-58-0
2-methoxyphenyl triflate

: o-(3-Cycloheptenyl)-anisol

: 92862-65-2
(E)-1-(2-methoxyphenyl)cyclohept-1-en

Guidance literature:: With 1,2-dimethoxybenzene; bis(1,1,1,5,5,5-hexafluoro-2,4-pentanedionato)palladium(II); 1,3-bis-(diphenylphosphino)propane; lithium carbonate; at 120 ℃; for 72h; Overall yield = 87 %; Overall yield = 88 mg; Inert atmosphere;
DOI:10.1002/chem.201204427